{"title":"分子内杂络合物形成对萘烷基胺和蒽烷基胺光反应性的影响","authors":"D. Brimage, R. Davidson","doi":"10.1039/C29710001385","DOIUrl":null,"url":null,"abstract":"Several NN-diethyl-1-naphthylalkylamines and NN-diethyl-9-anthrylalkylamines exhibit intramolecular exciplex formation and as a result reactions typical of the hydrocarbon singlet states, e.g. hydrogen abstraction from tertiary amines and dimerisation, are quenched.","PeriodicalId":17278,"journal":{"name":"Journal of The Chemical Society D: Chemical Communications","volume":"184 1","pages":"1385-1386"},"PeriodicalIF":0.0000,"publicationDate":"1971-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"18","resultStr":"{\"title\":\"Effect of intramolecular exciplex formation upon the photoreactivity of naphthylalkylamines and anthrylalkylamines\",\"authors\":\"D. Brimage, R. Davidson\",\"doi\":\"10.1039/C29710001385\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Several NN-diethyl-1-naphthylalkylamines and NN-diethyl-9-anthrylalkylamines exhibit intramolecular exciplex formation and as a result reactions typical of the hydrocarbon singlet states, e.g. hydrogen abstraction from tertiary amines and dimerisation, are quenched.\",\"PeriodicalId\":17278,\"journal\":{\"name\":\"Journal of The Chemical Society D: Chemical Communications\",\"volume\":\"184 1\",\"pages\":\"1385-1386\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1971-01-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"18\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of The Chemical Society D: Chemical Communications\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1039/C29710001385\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of The Chemical Society D: Chemical Communications","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1039/C29710001385","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Effect of intramolecular exciplex formation upon the photoreactivity of naphthylalkylamines and anthrylalkylamines
Several NN-diethyl-1-naphthylalkylamines and NN-diethyl-9-anthrylalkylamines exhibit intramolecular exciplex formation and as a result reactions typical of the hydrocarbon singlet states, e.g. hydrogen abstraction from tertiary amines and dimerisation, are quenched.
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