不同pH下合成木薯淀粉导电生物聚合物的电化学研究

A. Alvaro, E. M. Miguel, S. Manuel
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引用次数: 2

摘要

本研究的目的是确定pH值对木薯淀粉烷氧基化化学合成导电聚合物的电化学性能的影响,在不同的pH值(3,4,5,8,10,11,12)下,添加不同的增塑剂(甘油,戊二醛,聚乙二醇)和高氯酸锂。在pH值为4、5和8时,由于每一种测定的伏安图重叠,观察到它们的电化学结构具有更好的完整性,这表明每种材料的稳定性。最后,观察到材料的性质在极端pH条件下(非常低或非常高的pH)是不稳定的,证实了其结构的逐步重排。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Electrochemical Study of Cassava Starch Conductive Biopolymers Synthesized at Different pH
The aim of the study was to determine the effect of pH on the electrochemical properties of chemically-synthesized conductive polymers from alkoxylation of cassava starch at different pH (3, 4, 5, 8, 10, 11, 12) and with addition of different plasticizers (glycerol, glutaraldehyde, polyethylene glycol) and lithium perchlorate. The better integrity in their electrochemical structure was observed at pH 4, 5 and 8, due to the overlapping of the voltammograms of each one of the assays, indicating the stability of each material. Finally, it was observed that properties of the materials were unstable at extreme pH conditions (very low or very high pH), corroborating the progressive rearrangement of the structure thereof.
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