假单胞菌荧光C-2产生的细胞外生物聚合物作为生物吸附剂从水溶液中去除Ni (II)

Y. Mao, Zhong-fang Pei, Kui Zhang, Qingqing Hu, Yi Miao, Yan-feng Zhang, Xiao-Lin Lv
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引用次数: 1

摘要

本研究的目的是评估假单胞菌荧光C-2产生的胞外生物聚合物(PS-2)对合成废水中Ni(II)的环保性吸附。采用间歇式生物吸附法研究了PS-2对Ni(II)离子的去除能力。考察了pH、生物吸附剂用量、Ni(II)初始浓度、山梨酸与吸附剂接触时间和搅拌速度对PS-2吸附性能的影响。吸附平衡在60 min内迅速建立,吸附动力学符合准二级动力学模型。Langmuir等温线测定的Ni(II)的最大吸附量在pH 5.0、25±2℃、摇床转速150 rpm时分别为80.50 mg /g PS-2。扫描电镜(SEM)和傅里叶变换红外光谱(FTIR)结果表明,PS-2的羧基、羟基和氨基参与了与Ni(II)离子的化学相互作用。该研究指出了细胞外生物聚合物PS-2作为去除环境和工业废水中Ni (II)的有效生物吸附剂的新用途的潜力。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
An Extracellular Biopolymer Produced by Pseudomonas Fluorescence C-2 as Biosorbent to Remove Ni (II) from Aqueous Solutions
The objective of this study is to assess the environmentaly friendly Ni(II) adsorption from synthetic wastewater using extracellular biopolymer(PS-2) produced by Pseudomonas fluorescence C-2. The ability of PS-2 to remove the Ni(II) ions was investigated by using batch biosorption procedure. The effects such as pH, dosage of biosorbent, Ni(II) initial concentration and sorbate–sorbent contact time and agitating speed on the adsorption capacities of PS-2 were studied. Biosorption equilibriums were rapidly established in about 60 min and the adsorption kinetics followed the pseudo-second order kinetic model. The maximum Ni(II) adsorption capacity determined from Langmuir isotherm were 80.50 mg /g PS-2 at pH 5.0 ,at 25±2 ¿C and shaker speed 150 rpm, respectively. The carboxyl , hydroxyl and amino groups of the PS-2 were involved in chemical interaction with the Ni(II) ions depicted by scanning electron microscopic (SEM) and Fourier transform infrared spectroscopic (FTIR) results. The study points to the potential of new use of extracellular biopolymer PS-2 as an effective biosorbent for the removal of Ni (II) and from environmental and industrial wastewater.
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