石墨与改性聚烯烃纳米复合材料的物理力学性能

K. Allahverdiyeva
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引用次数: 0

摘要

研究了石墨浓度对高密度聚乙烯、低密度聚乙烯和聚丙烯等聚烯烃基纳米复合材料主要物理力学性能的影响。分析了拉伸屈服应力、极限拉伸应力、极限弯曲强度、断裂伸长率、耐热性、弯曲强度、MFI和熔点等性能。为了提高混合物混合组分的相容性,我们对所有等级的聚乙烯使用了Exxelor PO1040相容剂,对聚丙烯使用了Exxelor PO1020相容剂。将石墨以1.0、3.0、5.0、10%、15%、20%和30% wt%的浓度加入到聚烯烃的组成中。研究结果表明,在聚烯烃的组成中引入石墨后,其强度特性得到改善,且在不同浓度下均达到最大。对于高密度聚乙烯,强度特性的最大值在3.0 wt%时观察到,对于低密度聚乙烯在10 wt%时观察到,对于石墨含量为5.0 wt%的聚丙烯。结果表明,提供强度指标最大值的石墨阈值浓度的差异与聚合物基体的结晶度直接相关。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
PHYSICAL-MECHANICAL PROPERTIES OF NANOCOMPOSITES BASED ON GRAPHITE AND MODIFIED POLYOLEFINS
The influence of the graphite concentration on the main physical-mechanical properties of nanocomposites based on such polyolefin as high density polyethylene, low density polyethylene and polypropylene is considered. Properties such as tensile yield stress, ultimate tensile stress, and ultimate bending strength, elongation at break, heat resistance, flexural strength, MFI, and melting points are analysed. To improve the compatibility of the mixed components of the mixture, we used an Exxelor PO1040 compatibilizer for all grades of polyethylene and Exxelor PO1020 for polypropylene. Graphite was introduced into the composition of polyolefin at the following concentrations: 1.0, 3.0, 5.0, 10, 15, 20, and 30 wt%. As a result of the research, it was found that the introduction of graphite into the composition of polyolefin was accompanied by an improvement in strength characteristics with maximum at various concentrations. For high density polyethylene, the maximum values of strength characteristics are observed at 3.0 wt%, for low density polyethylene at 10 wt%, and for polypropylene at 5.0 wt% content of graphite. It revealed that such a difference in the value of the threshold concentration of graphite which provides the maximum value of strength indicators,was directly related to the degree of crystallinity of the polymer matrix.
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