用分子氘或9,10 -二氢蒽还原铂富勒化物

Fullerene Science and Technology Pub Date : 2000-11-01 DOI:10.1080/10641220009351431

N. Goldshleger, B. Tarasov, Y. Shul’ga, O. S. Roschupkina, A. A. Perov, A. Okotrub, A. P. Moravsky

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引用次数: 1

摘要

C60Pt与D2反应(D2压力为1 ~ 2 MPa, K为373 ~ 723 K)，生成C60Dx (x = 2 ~ 26)和Pt簇。铂中的C60也被二氢蒽还原为氢富勒烯。起始C60Pt中铂的EbPt4f7/2值(72.4 eV)表明C60Pt中的部分电荷从Pt原子转移到C60原子。

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Platinum Fulleride Reduction by Molecular Deuterium or 9, 10-dihydroanthracene

Abstract C60Pt reacts with D2 (1-2 MPa D2 pressure and 373-723 K) to form C60Dx (x = 2-26) and Pt clusters. C60 in platinum fulleride is also reduced by dihydroanthracene to hydrofullerenes. The value of EbPt4f7/2 (72.4 eV) obtained for platinum in the starting C60Pt suggests partial charge transfer from the Pt atom to C60 in C60Pt.

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Fullerene Science and Technology

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