{"title":"甘氨酸桥接三核Co(III)-Cu(II)-Co(III)配合物的合成、表征和解离","authors":"Ν. N. Das, A. Dash, G. S. Brahama, P. Mohanty","doi":"10.1515/irm-2003-0109","DOIUrl":null,"url":null,"abstract":"Abstract A trinuclear complex, [{(NH3)5Co(O2CCH2NH)}2Cu](ClO4)6.2H2O has been synthesised using mononuclear glycinato(pentaammine)cobalt(III) Perchlorate and characterised by various physicochemical methods. The kinetic study by stopped-flow spectrophotometer indicated that the dissociation of the trinuclear complex occurred mainly through an acid catalysed path.","PeriodicalId":8996,"journal":{"name":"BioInorganic Reaction Mechanisms","volume":"10 1","pages":"73 - 78"},"PeriodicalIF":0.0000,"publicationDate":"2003-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Synthesis, Characterisation and Dissociation of a Glycinate Bridged Trinuclear Co(III)-Cu(II)-Co(III) Complex\",\"authors\":\"Ν. N. Das, A. Dash, G. S. Brahama, P. Mohanty\",\"doi\":\"10.1515/irm-2003-0109\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Abstract A trinuclear complex, [{(NH3)5Co(O2CCH2NH)}2Cu](ClO4)6.2H2O has been synthesised using mononuclear glycinato(pentaammine)cobalt(III) Perchlorate and characterised by various physicochemical methods. The kinetic study by stopped-flow spectrophotometer indicated that the dissociation of the trinuclear complex occurred mainly through an acid catalysed path.\",\"PeriodicalId\":8996,\"journal\":{\"name\":\"BioInorganic Reaction Mechanisms\",\"volume\":\"10 1\",\"pages\":\"73 - 78\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2003-01-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"BioInorganic Reaction Mechanisms\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1515/irm-2003-0109\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"BioInorganic Reaction Mechanisms","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1515/irm-2003-0109","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Synthesis, Characterisation and Dissociation of a Glycinate Bridged Trinuclear Co(III)-Cu(II)-Co(III) Complex
Abstract A trinuclear complex, [{(NH3)5Co(O2CCH2NH)}2Cu](ClO4)6.2H2O has been synthesised using mononuclear glycinato(pentaammine)cobalt(III) Perchlorate and characterised by various physicochemical methods. The kinetic study by stopped-flow spectrophotometer indicated that the dissociation of the trinuclear complex occurred mainly through an acid catalysed path.
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