{"title":"γ - al2o3负载钼催化剂上乙烯氧化氨解制乙腈的研究","authors":"I. Peeters, V. Grondelle, V. Santen","doi":"10.1021/bk-1996-0638.ch023","DOIUrl":null,"url":null,"abstract":"Here we report the formation of CH 3 CN with ammonia and ethylene as starting materials over γ-Al 2 O 3 supported molybdenum catalysts. To focus on the reactivity of lattice oxygen and to exclude surface reoxidation, oxidative ammonolysis experiments were done in the absence of gazeous oxygen","PeriodicalId":20402,"journal":{"name":"Preprints-American Chemical Society Division of Petroleum Chemistry","volume":"62 2 1","pages":"75-78"},"PeriodicalIF":0.0000,"publicationDate":"1996-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"The oxidative ammonolysis of ethylene to acetonitrile over gamma-Al2O3 supported molybdenum catalysts\",\"authors\":\"I. Peeters, V. Grondelle, V. Santen\",\"doi\":\"10.1021/bk-1996-0638.ch023\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Here we report the formation of CH 3 CN with ammonia and ethylene as starting materials over γ-Al 2 O 3 supported molybdenum catalysts. To focus on the reactivity of lattice oxygen and to exclude surface reoxidation, oxidative ammonolysis experiments were done in the absence of gazeous oxygen\",\"PeriodicalId\":20402,\"journal\":{\"name\":\"Preprints-American Chemical Society Division of Petroleum Chemistry\",\"volume\":\"62 2 1\",\"pages\":\"75-78\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1996-01-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Preprints-American Chemical Society Division of Petroleum Chemistry\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1021/bk-1996-0638.ch023\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Preprints-American Chemical Society Division of Petroleum Chemistry","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1021/bk-1996-0638.ch023","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
The oxidative ammonolysis of ethylene to acetonitrile over gamma-Al2O3 supported molybdenum catalysts
Here we report the formation of CH 3 CN with ammonia and ethylene as starting materials over γ-Al 2 O 3 supported molybdenum catalysts. To focus on the reactivity of lattice oxygen and to exclude surface reoxidation, oxidative ammonolysis experiments were done in the absence of gazeous oxygen