4′-烷氧基-4-(ω-肉桂酰烷氧基)偶氮苯的合成及其光开关行为

ECSOC-25 Pub Date : 2021-11-14 DOI:10.3390/ecsoc-25-11685

Abdullah Al-Hemyari, Muna S. Bufaroosha, T. Thiemann

{"title":"4′-烷氧基-4-(ω-肉桂酰烷氧基)偶氮苯的合成及其光开关行为","authors":"Abdullah Al-Hemyari, Muna S. Bufaroosha, T. Thiemann","doi":"10.3390/ecsoc-25-11685","DOIUrl":null,"url":null,"abstract":": In search of new thermotropic, photoswitchable materials, a number of 4′ -alkoxy-4- (ω -cinnamoylalkoxy)azobenzenes were prepared. The synthetic procedure included O -alkylation of 4-nitrophenol, followed by reduction of the nitro group (H 2 , Pd/C), diazotization of the aniline and subsequent reaction with ω -hydroxyalkoxybenzenes, followed by a modified Appel-type esterification (BrCCl 3 , PPh 3 ). The photochemical behavior of the substances was investigated.","PeriodicalId":11441,"journal":{"name":"ECSOC-25","volume":"102 1","pages":""},"PeriodicalIF":0.0000,"publicationDate":"2021-11-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Synthesis of 4′-Alkoxy-4-(ω-cinnamoylalkoxy)azobenzenes and Their Photoswitchable Behavior\",\"authors\":\"Abdullah Al-Hemyari, Muna S. Bufaroosha, T. Thiemann\",\"doi\":\"10.3390/ecsoc-25-11685\",\"DOIUrl\":null,\"url\":null,\"abstract\":\": In search of new thermotropic, photoswitchable materials, a number of 4′ -alkoxy-4- (ω -cinnamoylalkoxy)azobenzenes were prepared. The synthetic procedure included O -alkylation of 4-nitrophenol, followed by reduction of the nitro group (H 2 , Pd/C), diazotization of the aniline and subsequent reaction with ω -hydroxyalkoxybenzenes, followed by a modified Appel-type esterification (BrCCl 3 , PPh 3 ). The photochemical behavior of the substances was investigated.\",\"PeriodicalId\":11441,\"journal\":{\"name\":\"ECSOC-25\",\"volume\":\"102 1\",\"pages\":\"\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2021-11-14\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"ECSOC-25\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.3390/ecsoc-25-11685\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"ECSOC-25","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.3390/ecsoc-25-11685","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}

引用次数: 0

摘要

为了寻找新的热致性和光开关材料，制备了一些4′-烷氧基-4- (ω -肉桂酰烷氧基)偶氮苯。合成过程包括4-硝基苯酚的O -烷基化，然后是硝基的还原(h2, Pd/C)，苯胺的重氮化，随后与ω -羟基烷氧苯反应，然后是改性的appel型酯化(brccl3, pph3)。研究了这些物质的光化学行为。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

查看原文本刊更多论文

Synthesis of 4′-Alkoxy-4-(ω-cinnamoylalkoxy)azobenzenes and Their Photoswitchable Behavior

: In search of new thermotropic, photoswitchable materials, a number of 4′ -alkoxy-4- (ω -cinnamoylalkoxy)azobenzenes were prepared. The synthetic procedure included O -alkylation of 4-nitrophenol, followed by reduction of the nitro group (H 2 , Pd/C), diazotization of the aniline and subsequent reaction with ω -hydroxyalkoxybenzenes, followed by a modified Appel-type esterification (BrCCl 3 , PPh 3 ). The photochemical behavior of the substances was investigated.

求助全文

通过发布文献求助，成功后即可免费获取论文全文。去求助

来源期刊

ECSOC-25

自引率

0.00%

发文量