利用聚乙二醇分子量的变化优化聚合物网络以椰子水纤维素菌为原料制备半IPN汗液凝胶

Tamrin, E. Zaidar
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引用次数: 0

摘要

研究了分子量变化对聚乙二醇1000的影响;研究了以细菌纤维素为原料,在椰子水中利用醋酸菌木聚糖系统发酵制备半互穿聚合物网络水凝胶。与使用聚乙二醇3000和聚乙二醇1000相比,聚乙二醇6000的IPN水凝胶具有更多的交联。采用peg 6000制备的热凝胶IPN的温度为457,14℃,与peg 3000制备的温度为252,80℃和peg 1000制备的温度为244,30℃进行了对比。采用交联率、傅立叶变换红外(FT-IR)光谱化学结构分析、吸水率测试和差热分析(DTA)对制备的半IPN水凝胶进行了表征。通过分析,他们发现使用PEG 6000的半互穿聚合物网络水凝胶的交联率最高(64.3%),PEG 3000的交联率为42.5%,PEG 1000的交联率为15%。7%。FTIR表征结果表明,聚丙烯酸与MBA之间存在交联反应。这表明存在1403 cm -1和1560 cm -1 (COO -)和3413 cm -1 (NH胺)。采用差热分析(DTA)方法对半ipn水凝胶进行了热稳定性分析,结果表明,在680℃下完全降解的半ipn水凝胶中加入聚烯六千醇时热稳定性最佳,分解过程中发生吸热和放热反应。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Optimization of Polymer Networks using Variations in Moleculer Weight of Polyetilen Glycol in the Manufacture of Semi – IPN Hidrogels from Coconut Water Cellulose Bacteria
: Research heve been done to find out the effect of variation moleculer weight polietylen glikoln 1000; 3000 and 6000 on manufacture semi interpenetrating polymer networks hidrogel from bacterial selulose with sytem fermentation using accetobacterial-xylinum in based coconut water. IPN hidrogel by polietilenglikol 6000 has more croslinks compared using peg 3000 and peg 1000. Analysis thermal hidrogel IPN using peg 6000 is 457,14 0 C, compared PEG 3000 is 252, 80 0 C and PEG 1000 is 249,30 0 C. semi-IPN hydrogel formed was characterized by, crosslink percentage, chemistry structural analysis using Fourier Transform Infrared (FT-IR) spectroscopy, water absorption test and thermal resistance using Differential Thermal Analysis (DTA). From the analysis, they showed Semi Interpenetrating Polymer Network Hydrogel with using PEG 6000 the highest crosslink percentage (64,3%) for PEG 3000 is 42.5 % and PEG 1000 is 15. 7 %. Characterization results of FTIR indicate the occurrence of crosslinking between Polyacrylic acid and MBA. This shown in existence of 1403 cm -1 and 1560 cm -1 (COO - ) and 3413 cm -1 (NH amine). Thermal analysis using Differential Thermal Analysis (DTA) shows thermal optimum thermal stability at the addition of Polietilengiikol 6000 to semi-IPN hydrogel which was completely degraded at 680 o C, reaction that occurs during the decomposition process is endothermic and exothermic reaction.
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