6-偕二硝基乙烯基-4,5,8-三硝基-5,6,7,8-四氢化-4H-咪唑烷并[4,5-e]呋咱并[3,4-b]哌嗪的合成

Q3 Engineering

Hanneng Cailiao/Chinese Journal of Energetic Materials Pub Date : 2014-01-01 DOI:10.3969/j.issn.1006-9941.2014.02.031

霍欢, 王伯周, 廉鹏, 来蔚鹏, 李辉, 葛忠学

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引用次数: 0

摘要

以FOX-7和乙二醛为原料,经过两步缩合环化反应和硝化反应,首次设计并合成出了一种新型的呋咱稠环硝胺化合物6-偕二硝基乙烯基-4,5,8-三硝基-5,6,7,8-四氢化-4H-咪唑烷并[4,5-e]呋咱并[3,4-b]哌嗪（PNEIFP）。采用Gaussian 09程序和VLW方程计算PNEIFP的密度、生成焓和爆速分别为2.02 g·cm^-3、724.1 kJ·mol^-1和9681.0 m·s^-1。利用TLC跟踪实验的方法,确定PNEIFP室温下易分解。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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6-偕二硝基乙烯基-4,5,8-三硝基-5,6,7,8-四氢化-4H-咪唑烷并[4,5-e]呋咱并[3,4-b]哌嗪的合成

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来源期刊

Hanneng Cailiao/Chinese Journal of Energetic Materials Engineering-Industrial and Manufacturing Engineering

CiteScore

1.90

自引率

0.00%

发文量

4271

期刊介绍： Chinese Journal of Energetic Materials is a vital forum for the exchange of science and technology in energetic materials, and information on - Propellants - Explosives - Pyrotechnics - Ignition, combustion and detonation