煤焦油电弧放电法低成本合成单壁碳纳米管

M. Saha
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摘要

在催化剂颗粒存在下生长CNTs的方法有电弧放电、激光烧蚀、化学气相沉积(CVD)、模板定向合成等多种方法。利用电弧放电技术,以廉价的煤作为起始碳源,可以大批量生产碳纳米管。研究发现,在碳纳米管呈巢状排列的阴极沉积层中,可以获得大量质量良好的碳纳米管。二十多年来,人们对碳纳米管的生产及其工艺优化进行了广泛的研究。据信,它们是人类已知的足够坚固但最具柔韧性的材料。他们有潜力参与到新的纳米制造材料中。众所周知,碳纳米管具有优异的力学性能,可以作为一种终极的一维材料。此外,碳纳米管还具有很强的导电性和导热性。本文主要研究与产品批量生产有关的这些参数的优化问题。单纯形法表明,基于电弧放电技术获得的单壁碳纳米管的成本,电压和电流应分别在30 - 42 V和49 - 66 A范围内。高于给定值的任何组合都将导致功率消耗成本超过最终产品成本,从而导致工艺不可行。人们对碳纳米管作为复合材料在未来许多工业中的应用有着强烈的期望。这种材料的生产成本、纯度和性能的控制将影响纳米管对化学、计算机和建筑行业的影响。在这种情况下,煤的性质也很重要。煤中的弱键和矿物在纳米管的形成中起着重要作用。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Low Cost Synthesis of Single Walled Carbon Nanotubes from Coal Tar Using Arc Discharge Method
There are various methods such as arc discharge, laser ablation, chemical vapour deposition (CVD), template-directed synthesis for the growth of CNTs in the presence of catalyst particles. The production of carbon nanotubes in large quantities is possible with inexpensive coal as the starting carbon source by the arc discharge technique. It is found that a large amount of carbon nanotubes of good quality can be obtained in the cathode deposits in which carbon nanotubes are present in nest-like bundles. For more than two decades, now, there has been extensive research on the production of carbon nanotubes (CNT) and optimization of its manufacture for the industrial applications. It is believed that they are the strong enough but most flexible materials known to mankind. They have potential to take part in new nanofabricated materials. It is known that, carbon nanotubes could behave as the ultimate one-dimensional material with remarkable mechanical properties. Moreover, carbon nanotubes exhibit strong electrical and thermal conducting properties. This paper primarily concentrates on the optimising such parameters related to the mass production of the product. It has been shown through Simplex process that based on the cost of the SWNT obtained by the arc discharge technique, the voltage and the current should lie in the range of 30 42 V and 49 66 A respectively. Any combination above the given values will lead to a power consumption cost beyond the final product cost, in turn leading to infeasibility of the process. Strong expectations exist for future use of carbon nanotubes as composite materials in a large number of industries. Production cost and control of the purity and properties of such materials will influence the impacts nanotubes on the chemical, computer and construction industries. Coal properties in this case are also important. Weak bonds and mineral matter in the coal play an important role in the formation of the nanotubes.
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