21章。金属-有机骨架在CO2捕集与转化中的应用

Li Zhang, Jiewei Liu, C. Su
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引用次数: 2

摘要

金属有机骨架(mof)具有显著的性能,包括大表面积、开放通道和永久孔隙,是二氧化碳捕获和转化的有希望的候选者。通过合理选择金属簇和有机连接体,可以实现具有理想拓扑结构的框架。此外,对mof中非共价相互作用的研究为了解mof的催化性能与框架结构之间的关系提供了重要的见解,这也将进一步促进mof作为二氧化碳捕获和转化的多相催化剂的发展。本章共分为四节。第一部分简要介绍了MOFs的结构和化学特性。第二部分集中于mof作为有机化合物与CO2化学固定的多相催化剂。第三部分介绍了mof作为CO2还原光催化剂的作用。最后一节介绍了MOFs在电催化还原CO2中的应用。强调了合理设计和应用MOF催化剂所面临的特殊挑战以及进一步发展的研究机会。希望本章不仅能成为深入了解这一具有挑战性的领域的起点,而且还能激发对创造性MOFs作为二氧化碳捕获和转化的多相催化剂的发展进行更深入的研究。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
CHAPTER 21. Application of Metal–Organic Frameworks in CO2 Capture and Conversion
Metal–organic frameworks (MOFs) are promising candidates for CO2 capture and conversion as they possess remarkable properties, including large surface area, open channels and permanent porosity. Through the judicious selection of metal clusters and organic linkers, a framework with a desired topology can be realized. Furthermore, the study of the noncovalent interactions in MOFs provides significant insights into the relationship between the catalytic performance and the framework structure, which will also further promote the development of MOFs as heterogeneous catalysts for CO2 capture and conversion. This chapter is divided into four sections. The first section gives a brief introduction to the structures and chemical features of MOFs. The second section concentrates on MOFs as heterogeneous catalysts for the chemical fixation of CO2 with organic compounds. The third section presents MOFs as photocatalysts for CO2 reduction. The last section covers the application of MOFs in the electrocatalytic reduction of CO2. Particular challenges in the rational design and application of MOF catalysts and research opportunities for further development are highlighted. It is hoped that this chapter will not only serve as a starting point to gain insights into this challenging field but will also stimulate more intensive research on the development of creative MOFs as heterogeneous catalysts towards CO2 capture and conversion.
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