瓜[8]脲与1-(4-甲氧基苯基)哌嗪超分子结构的构建

Journal of Chemical Research-s Pub Date : 2022-03-01 DOI:10.1177/17475198221106398

Jun Zheng, Lin Zhang, Yuhe Chen, Yue Ma, Xue Dai, L. Shi, Yanli Lu, Xinan Yang, P. Ma

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引用次数: 0

摘要

我们报道了瓜[8]脲(Q[8])和1-(4-甲氧基苯基)哌嗪包合物的超分子自组装。在CdCl2诱导条件下，在3 M盐酸溶液中培养该配合物，得到一个新的晶体，并用x射线单晶衍射对其结构进行了表征。结果表明，该晶体属于C2/m空间群的单斜晶系。Q[8]与1-(4-甲氧基苯基)哌嗪的主客体相互作用比为1:2。

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Construction of a supramolecular framework consisting of cucurbit[8]uril and 1-(4-methoxyphenyl)piperazine

We report the supramolecular self-assembly of cucurbit[8]uril(Q[8]) and 1-(4-methoxyphenyl)piperazine inclusion complex. The complex is cultured in 3 M hydrochloric acid solution under CdCl2 induction conditions to obtain a new crystal, the structure of which was characterized by X-ray single-crystal diffraction. The results show that the crystal belongs to the monoclinic crystal system with a C2/m space group. The host–guest interaction ratio of Q[8] and 1-(4-methoxyphenyl) piperazine is 1:2.

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来源期刊

Journal of Chemical Research-s 化学科学, 有机化学, 有机合成

自引率

0.00%

发文量

审稿时长

1 months

期刊介绍： The Journal of Chemical Research is a peer reviewed journal that publishes full-length review and research papers in all branches of experimental chemistry. The journal fills a niche by also publishing short papers, a format which favours particular types of work, e.g. the scope of new reagents or methodology, and the elucidation of the structure of novel compounds. Though welcome, short papers should not result in fragmentation of publication, they should describe a completed piece of work. The Journal is not intended as a vehicle for preliminary publications. The work must meet all the normal criteria for acceptance as regards scientific standards. Papers that contain extensive biological results or material relating to other areas of science may be diverted to more appropriate specialist journals. Areas of coverage include: Organic Chemistry; Inorganic Chemistry; Materials Chemistry; Crystallography; Computational Chemistry.