{"title":"简单高效的氧化剂Pd(OAc) 2催化可循环室温离子液体(RTIL)在空气存在下选择性氧化烷基/苯甲醇","authors":"M. Anand, Monika Gupta, A. Gupta, Rajive Gupta","doi":"10.2174/1876214X01003010092","DOIUrl":null,"url":null,"abstract":"Trimethyl pyrazolium tetrafluoroborate room-temperature ionic liquid was prepared and employed for the selective oxidation of alkyl/benzyl alcohols using palladium acetate by stirring at room-temperature in presence of air (oxygen from air). This green procedure gave products in moderate to good yields. Moreover, the synthesized 1,3,5- trimethylpyrazolium tetrafluoroborate ionic liquid could be recycled for at least three runs without the loss of significant activity.","PeriodicalId":22755,"journal":{"name":"The Open Catalysis Journal","volume":"17 1","pages":"92-97"},"PeriodicalIF":0.0000,"publicationDate":"2010-10-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"1","resultStr":"{\"title\":\"A Simple and Efficient Oxidant Pd(OAc) 2 Catalyzed Selective Oxidation of Alkyl/Benzyl Alcohols in Presence of Air Using Recyclable Room-Temperature Ionic Liquid (RTIL)\",\"authors\":\"M. Anand, Monika Gupta, A. Gupta, Rajive Gupta\",\"doi\":\"10.2174/1876214X01003010092\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Trimethyl pyrazolium tetrafluoroborate room-temperature ionic liquid was prepared and employed for the selective oxidation of alkyl/benzyl alcohols using palladium acetate by stirring at room-temperature in presence of air (oxygen from air). This green procedure gave products in moderate to good yields. Moreover, the synthesized 1,3,5- trimethylpyrazolium tetrafluoroborate ionic liquid could be recycled for at least three runs without the loss of significant activity.\",\"PeriodicalId\":22755,\"journal\":{\"name\":\"The Open Catalysis Journal\",\"volume\":\"17 1\",\"pages\":\"92-97\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2010-10-29\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"1\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"The Open Catalysis Journal\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.2174/1876214X01003010092\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"The Open Catalysis Journal","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.2174/1876214X01003010092","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
A Simple and Efficient Oxidant Pd(OAc) 2 Catalyzed Selective Oxidation of Alkyl/Benzyl Alcohols in Presence of Air Using Recyclable Room-Temperature Ionic Liquid (RTIL)
Trimethyl pyrazolium tetrafluoroborate room-temperature ionic liquid was prepared and employed for the selective oxidation of alkyl/benzyl alcohols using palladium acetate by stirring at room-temperature in presence of air (oxygen from air). This green procedure gave products in moderate to good yields. Moreover, the synthesized 1,3,5- trimethylpyrazolium tetrafluoroborate ionic liquid could be recycled for at least three runs without the loss of significant activity.
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