鲁米诺固定化阴离子交换树脂作为化学发光氧气传感器的指示相

Takuya Okamoto, Ken-ichiro Tanaka, H. Goto, Jin‐Ming Lin, M. Yamada, Y. Asano
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引用次数: 6

摘要

研究了固定在强碱性阴离子交换树脂上的指示相鲁米诺对N2气体中O2的化学发光传感性能。用安装在流池中的硅光电二极管监测碱催化的鲁米诺化学发光,其中填充了负载鲁米诺的树脂。信号明显依赖于固定化所用的树脂和溶剂。通过注射1毫升样品,测定了氮气和城市气体中ppm水平的氧气浓度。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Luminol immobilized anion-exchange resin as an indicator phase for a chemiluminescence oxygen gas sensor
An indicator phase, luminol immobilized on a strongly basic anion-exchange resin, was evaluated for the chemiluminescence sensing of O2 in N2 gas. The base catalyzed luminol chemiluminescence was monitored with a silicon photodiode installed in a flow cell, into which the luminol-loaded resin was packed. The signal was dependent significantly on resins and solvents used for the immobilization. Oxygen gas concentrations at ppm levels in a N2 gas and a city gas were determined by means of 1 ml sample injection.
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