{"title":"乙烯类化合物与有机过氧化物的环氧化和羟基化反应","authors":"D. Swern","doi":"10.1002/0471264180.OR007.07","DOIUrl":null,"url":null,"abstract":"Oxiranes and alpha-glycols can be prepared from olefins by a variety of methods. One of the most important and generally applicable of these is the oxidation of ethylenic compounds with organic peracids. Depending on the peracid employed and/or operating conditions either an oxirane or an alpha-glycol can be obtained in good yield. It is important to note that the oxidation step both in epoxidation and hydroxylation reactions with organic peracids is the conversion of the olefin to the oxirane. \n \n \nKeywords: \n \nepoxidation; \nhydroxylation; \nethylenic compound; \norganic peracids; \nstereochemistry; \nexperimental conditions","PeriodicalId":19539,"journal":{"name":"Organic Reactions","volume":"27 1","pages":"378-434"},"PeriodicalIF":0.0000,"publicationDate":"2011-03-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"12","resultStr":"{\"title\":\"Epoxidation and Hydroxylation of Ethylenic Compounds with Organic Peracids\",\"authors\":\"D. Swern\",\"doi\":\"10.1002/0471264180.OR007.07\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Oxiranes and alpha-glycols can be prepared from olefins by a variety of methods. One of the most important and generally applicable of these is the oxidation of ethylenic compounds with organic peracids. Depending on the peracid employed and/or operating conditions either an oxirane or an alpha-glycol can be obtained in good yield. It is important to note that the oxidation step both in epoxidation and hydroxylation reactions with organic peracids is the conversion of the olefin to the oxirane. \\n \\n \\nKeywords: \\n \\nepoxidation; \\nhydroxylation; \\nethylenic compound; \\norganic peracids; \\nstereochemistry; \\nexperimental conditions\",\"PeriodicalId\":19539,\"journal\":{\"name\":\"Organic Reactions\",\"volume\":\"27 1\",\"pages\":\"378-434\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2011-03-15\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"12\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Organic Reactions\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1002/0471264180.OR007.07\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Organic Reactions","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1002/0471264180.OR007.07","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Epoxidation and Hydroxylation of Ethylenic Compounds with Organic Peracids
Oxiranes and alpha-glycols can be prepared from olefins by a variety of methods. One of the most important and generally applicable of these is the oxidation of ethylenic compounds with organic peracids. Depending on the peracid employed and/or operating conditions either an oxirane or an alpha-glycol can be obtained in good yield. It is important to note that the oxidation step both in epoxidation and hydroxylation reactions with organic peracids is the conversion of the olefin to the oxirane.
Keywords:
epoxidation;
hydroxylation;
ethylenic compound;
organic peracids;
stereochemistry;
experimental conditions
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