锶掺杂对凝胶生长铜镉和草酸钴镉晶体热光学性能的影响

P. S. Rohith, N. Jagannatha, Pradeepkumar K.V
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引用次数: 2

摘要

本文采用单扩散法制备了Sr掺杂的草酸铜镉(CuCO)和草酸钴镉(CoCO)晶体。通过改变不同的生长参数,确定了晶体生长的最佳条件。能量色散x射线分析(EDX)证实了生长晶体晶格中存在Sr 2+、Co 2+、Cu 2+、Cd 2+等主要元素。利用热重分析(TGA)研究了生长晶体的失重率、分子量和热稳定性。利用紫外可见光谱法计算了晶体的能隙、折射率、反射率和电极化率。直接带隙和间接带隙用陶克图计算。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Effect of Strontium doping on Thermal and Optical properties of Gel grown Copper cadmium and Cobalt cadmium oxalate crystals
In the present paper, the Sr doped Copper cadmium oxalate (CuCO) and Cobalt cadmium oxalate (CoCO) crystals were grown by the single diffusion method in silica hydrogel at room temperature. Optimum conditions of the as-grown crystals were established by varying different growth parameters. Energy-dispersive X-ray analysis (EDX) confirmed the presence of major elements such as Sr 2+ , Co 2+ , Cu 2+ , Cd 2+ ions in the lattice of the grown crystals. The percentage weight loss, molecular weight and thermal stability of the grown crystals were studied using Thermogravimetric analysis (TGA). The Energy gap, refractive index, reflectance and electrical polarizability of the crystals were calculated by using UVVisible spectroscopy. Direct and Indirect band gaps are calculated using Tauc’s plot.
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