甲基丙烯酸丁酯与环丙基苯乙烯及其氯化衍生物的共聚反应

S. B. Mamedli
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引用次数: 0

摘要

研究了甲基丙烯酸丁酯与对环丙基苯乙烯(I)及其单氯- (II)、双氯取代衍生物(III)的自由基共聚反应,揭示了功能取代环丙基苯乙烯形成的基本规律。确定了合成共聚物的组成和结构。确定了共聚常数,计算了共聚物的Alfrey-Price Q-e参数和微观结构。结果表明,新共聚物具有良好的光学指数(nD20 =1.640 ~ 1.650)。对于400 ~ 1100 nm范围内的BMA + (I-III)共聚物,基光透过率为88 ~ 90%。结果表明,由这些单体得到的共聚物具有良好的塑性,可用于制造具有良好开发性能的小尺寸注塑制品。BMA + (I−III)共聚物的特征粘度为[η] = 0.90 ~ 1.02 dl/g。BMA +氯化环丙基苯乙烯共聚物表现为不燃性,而BMA-苯乙烯共聚物表现为自熄性。所得共聚物比聚苯乙烯本身具有更大的热稳定性。以氯代环丙烷为基材制备的共聚物具有光学透明性,这是其在光学领域应用的重要特性。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Copolymerization of butyl methacrylate with cyclopropyl styrene and its chlorinated derivatives
The radical copolymerization of butyl methacrylate with p-cyclopropyl styrene (I) and its monochlorine- (II), gemdichlorine-substituted derivatives (III) has been carried out and the basic regularities of formation of functionally substituted cyclopropyl styrene have been revealed. The composition and structure of the synthesized copolymers have been established. The copolymerization constants have been determined, the Alfrey–Price Q–e parameters and the microstructure of copolymers have been calculated. It has been established that the new copolymers are characterized by good optical indices (nD20 =1.640−1.650). For BMA + (I–III) copolymers in the range of 400−1100 nm, the base light transmission is 88−90%. It has been shown that the copolymers obtained from these monomers show excellent plasticity, due to which they can be used in making of small-sized injection molding products with improved exploitation properties. The characteristic viscosity of BMA + (I−III) copolymers is [η] = 0.90−1.02 dl/g. The copolymers based on BMA + chlorinated cyclopropyl styrene show incombustibility, whereas BMA-styrene copolymers are self-extinguishing. It has been found that the obtained copolymers show greater thermal stability than polystyrene itself. The copolymers obtained on the basis of chloro-substituted cyclopropane show optical transparency, which is an important characteristic for their application in optics.
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