用辣木籽提取物处理制革厂废水

Shetie Gatew, W. Mersha
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引用次数: 4

摘要

环境中含有大量的重金属离子,如铬,对动物和人类的健康都是有害的。生物吸附制革废水中的铬是制革工业中化学处理的一种替代方法。因此,本研究考察了辣木籽提取物对制革废水中铬的吸附效果。研究了溶液pH、吸附剂浓度、Cr初始浓度、接触时间和温度对辣木籽提取物对制革废水中Cr的吸附效果的影响。结果表明,在强酸性条件下,辣木籽提取物对Cr的去除效果较差,而本研究结果表明,辣木籽提取物在浓度为1g/100 ml、pH为9.5的条件下,可使制革废物中Cr的浓度降低99.86%。此外,利用Langmuir、Freundlich、Dubinin-Radushkevich和Temkin等温模型对吸附数据进行了关联。在所研究的模型中,Dubinin-Radushkevich等温线拟合最佳,相关系数为0.958。此外,还计算了吉布斯自由能(AGo)、焓(AHo)和熵(ASo)等热力学参数。结果表明,辣木种子提取物对铬的生物吸附是自发的、可行的、吸热的。研究结果表明,辣木籽提取物可用于制革废水中铬的去除。关键词:辣木,铬,制革,pH,温度,浓度
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Tannery wastes water treatment using Moringa Stenopetala seed extract
High amount of heavy metal ions like Cr in the environment has been harmful for animal and human health. Bioadsorption of Cr from tannery wastes would be an alternative method to the chemical treatment in tannery industries. Hence, in this study the efficiency of Moringa  stenopetala seed extract to adsorption Cr from tannery waste water was investigated. The influence of solution pH, adsorbent concentration, initial concentration of Cr, contact time and temperature on the efficiency of Moringa stenopetala seed extract for the adsorption of Cr from tannery effluent was studied. Results obtained revealed that in strongly acidic condition Moringa stenopetala seed extract was less efficient to remove Cr. However, the result of the present study showed that Moringa stenopetala seed extract at a concentration of 1g/100 ml and pH of 9.5 decreased the concentration of Cr in tannery waste by 99.86%. In addition, the adsorption data was correlated using the Langmuir, Freundlich, Dubinin-Radushkevich, and Temkin isotherm models. Among models studied Dubinin-Radushkevich isotherm was the best fit with correlation coefficient of 0.958. Moreover, thermodynamics parameters, such as Gibbs free energy (AGo), enthalpy (AHo), and entropy (ASo) were calculated. Results indicated that the bioadsorption of Cr by Moringa stenopetal a seed extract was  spontaneous, feasible and endothermic. The results of this study proved that Moringa stenopetala seed extract can be used to remove Cr from tannery effluent. KEYWORDS : Moringa stenopetala , Cr, tannery, pH, temperature, concentration
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