氧化过程中烷烃和烷基自由基诱导二甲基二氧环烷均解。分子氧和自由基抑制剂的显著作用

A. Bravo, F. Fontana, G. Fronza, A. Mele, F. Minisci
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引用次数: 13

摘要

二甲基二氧环对烷烃的氧化受到分子氧和自由基抑制剂的显著影响,这支持了自由基机制对这些极具选择性反应的假设;提出了影响自由基选择性的因素。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Induced homolysis of dimethyldioxirane by alkanes and alkyl radicals in oxidation processes. The dramatic role of molecular oxygen and radical inhibitors
The oxidation of alkanes by dimethyldioxirane is dramatically affected by the presence of molecular oxygen and radical inhibitors, supporting the hypothesis of a free-radical mechanism for these extraordinarily selective reactions; the factors affecting the free-radical selectivity are suggested.
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