老化过程中单体体系对树脂复合材料与聚合纤维增强复合材料粘结强度的影响

A. Khan, B. A. Mohamed, S. Al-Shamrani, Ravikumar Ramakrishnaiah, Leila Perea-Lowery, E. Säilynoja, P. Vallittu
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引用次数: 11

摘要

目的研究不同单体体系对树脂复合材料和聚合纤维增强复合材料(FRC)之间拉伸结合强度的影响。在准备FRC基材进行粘合试验之前,还评估了FRC预浸料(用树脂体系预浸渍的增强纤维)的龄期(保质期)的影响。材料和方法半互穿聚合物网络(semi-IPN)基玻璃FRC预浸料在4°C下老化不同时间(1年、1.5年和3年),然后通过光聚合制备FRC基板。采用不同的处理方法制备四组老化前浸料:1。没有底漆;2. 二甲基丙烯酸酯基胶粘剂底漆;3.万能底漆;和4。特定的复合底漆。随后,在处理后的FRC基材上涂上树脂复合水泥,并进行光固化。测定了frp -复合材料试样的吸水率。然后,采用方差分析(ANOVA)评估拉伸粘结强度的差异(p≤0.05)。结果复合水泥与FRC的抗拉强度根据底漆的使用(p < 0.001)、老化时间(p < 0.001)和相互作用(p < 0.001)存在显著差异。结论通用引物的单体在FRC聚合物基质的半ipn结构中扩散能力最好。这提高了复合水泥与FRC基板之间的界面结合强度。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Influence of Monomer Systems on the Bond Strength Between Resin Composites and Polymerized Fiber-Reinforced Composite upon Aging.
PURPOSE This study examined the influence of different monomer systems on the tensile bond strength between a resin composite and a polymerized fiber-reinforced composite (FRC). The influence of the age (shelf-life) of the FRC prepreg (reinforcing fiber pre-impregnated with a resin system) before preparing the FRC substrate for the bonding test was also assessed. MATERIALS AND METHODS Semi-interpenetrating polymer network (semi-IPN)-based glass FRC prepregs were aged for various durations (1, 1.5, and 3 years) at 4°C before being used to prepare FRC substrates via light polymerization. Four groups of aged prepregs were prepared through different treatments with: 1. no primer; 2. a dimethacrylate-based adhesive primer; 3. a universal primer; and 4. a specific composite primer. Subsequently, a resin composite luting cement was applied on the treated FRC substrates and cured with light. The water sorption of the FRC-composite specimens was determined. Then, the differences in the tensile bond strength were evaluated using ANOVA (p ≤ 0.05). RESULTS There were significant differences in the tensile bond strength between the composite cement and the FRC according to the primer used (p < 0.001), aging time (p < 0.001), and their interactive effect (p < 0.001). CONCLUSION The monomers of the universal primer demonstrated the best ability to diffuse into the semi-IPN structure of the polymer matrix of FRC. This improved the interfacial bond strength between the composite cement and the FRC substrate.
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