{"title":"聚苯乙烯负载氯化铝银作为选择性乙烯吸附剂","authors":"H. Hirai, S. Hara, M. Komiyama","doi":"10.1002/APMC.1985.051300118","DOIUrl":null,"url":null,"abstract":"Polystyrene-supported aluminium silver chloride was prepared as a solid and selective adsorbent for ethylene by refluxing silver chloride, aluminium chloride, and macroreticular-type polystyrene resin in carbon disulfide, followed by removal of the solvent in vacuo. The adsorbent rapidly adsorbed ethylene about equimolar to aluminium silver chloride under 1 atm at 20°C. Almost all the ethylene adsorbed was released by subjecting the adsorbent to a reduced pressure 8 mm Hg at 20°C for 10 min. The adsorbent, however, showed no adsorption of carbon monoxide under 1 atm at 20°C.","PeriodicalId":7808,"journal":{"name":"Angewandte Makromolekulare Chemie","volume":"22 1","pages":"207-212"},"PeriodicalIF":0.0000,"publicationDate":"1985-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"20","resultStr":"{\"title\":\"Polystyrene‐supported aluminium silver chloride as selective ethylene adsorbent\",\"authors\":\"H. Hirai, S. Hara, M. Komiyama\",\"doi\":\"10.1002/APMC.1985.051300118\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Polystyrene-supported aluminium silver chloride was prepared as a solid and selective adsorbent for ethylene by refluxing silver chloride, aluminium chloride, and macroreticular-type polystyrene resin in carbon disulfide, followed by removal of the solvent in vacuo. The adsorbent rapidly adsorbed ethylene about equimolar to aluminium silver chloride under 1 atm at 20°C. Almost all the ethylene adsorbed was released by subjecting the adsorbent to a reduced pressure 8 mm Hg at 20°C for 10 min. The adsorbent, however, showed no adsorption of carbon monoxide under 1 atm at 20°C.\",\"PeriodicalId\":7808,\"journal\":{\"name\":\"Angewandte Makromolekulare Chemie\",\"volume\":\"22 1\",\"pages\":\"207-212\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1985-03-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"20\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Angewandte Makromolekulare Chemie\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1002/APMC.1985.051300118\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Angewandte Makromolekulare Chemie","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1002/APMC.1985.051300118","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 20
摘要
通过将氯化银、氯化铝和大孔型聚苯乙烯树脂在二硫化碳中回流,真空脱除溶剂,制备了聚苯乙烯负载型氯化铝银作为乙烯的固体选择性吸附剂。吸附剂在20℃下,在1atm下将等摩尔的乙烯快速吸附到氯化铝银上。在20℃下,将吸附剂减压8 mm Hg,持续10 min,几乎所有吸附的乙烯都被释放。然而,在20℃下,吸附剂在1 atm下没有吸附一氧化碳。
Polystyrene‐supported aluminium silver chloride as selective ethylene adsorbent
Polystyrene-supported aluminium silver chloride was prepared as a solid and selective adsorbent for ethylene by refluxing silver chloride, aluminium chloride, and macroreticular-type polystyrene resin in carbon disulfide, followed by removal of the solvent in vacuo. The adsorbent rapidly adsorbed ethylene about equimolar to aluminium silver chloride under 1 atm at 20°C. Almost all the ethylene adsorbed was released by subjecting the adsorbent to a reduced pressure 8 mm Hg at 20°C for 10 min. The adsorbent, however, showed no adsorption of carbon monoxide under 1 atm at 20°C.