分子间复合物低频振动的红外量子级联激光光谱

2011 International Conference on Infrared, Millimeter, and Terahertz Waves Pub Date : 2011-12-15 DOI:10.1109/IRMMW-THZ.2011.6104772

B. McElmurry, L. Rivera-Rivera, K. W. Scott, R. Lucchese, Zhongcheng Wang, I. Leonov, A. Legon, J. Bevan

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引用次数: 1

摘要

报道了基于QCL的谱仪在CO和HX (X= F, Cl, CN, CCH)连续波超音速狭缝射流膨胀中的应用。对CO拉伸振动的基本、组合和热带的光谱分析提供了低频分子间振动的反振动参数，可用于确定各自二聚体的变形势。

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Infrared quantum cascade laser spectroscopy of low frequency vibrations of intermolecular complexes

Application of a QCL based spectrometer to cw supersonic slit jet expansions of CO and HX (X= F, Cl, CN, CCH) are reported. Spectroscopic analysis of fundamental, combination and hot bands of the CO stretching vibrations provide ro-vibrational parameters for low frequency intermolecular vibrations that can be incorporated in determination of morphed potentials for the respective dimers.

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来源期刊

2011 International Conference on Infrared, Millimeter, and Terahertz Waves

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