刚性棒和柔性聚合物非热混合物的相行为

R. Sear
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引用次数: 8

摘要

研究了棒状聚合物和柔性聚合物的溶变混合物。棒状聚合物是由硬杆和柔性聚合物的自我避免行走建模。研究了棒状聚合物和柔性聚合物之间的相互作用,发现了这种相互作用强制脱混的趋势。考虑到与螺旋生物聚合物和柔性聚合物的混合物有关,棒材的直径要比柔性聚合物的片段直径大得多,但比其旋转半径小得多。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Phase Behaviour of Athermal Mixtures of Rigid-Rod and Flexible Polymers
Lyotropic mixtures of rodlike and flexible polymers are studied. The rodlike polymer is modelled by a hard rod and the flexible polymer by a self-avoiding walk. The interaction between rodlike and flexible polymers is studied and a tendency for this interaction to force demixing is found. Diameters of the rod which are much larger than the diameter of the segments of the flexible polymer but much smaller than its radius of gyration are considered because of their relevance to mixtures of helical biopolymers and flexible polymers.
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