一种5-甲氧基二苯甲酸锌配合物的合成、晶体结构及发光性能

Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry Pub Date : 2016-04-02 DOI:10.1080/15533174.2014.988799

Meili Zhang

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引用次数: 0

摘要

合成了一种新的Zn(II)配合物{[Zn2(ch30 -ip)2(bib)]·(H2O)}n (1) (ch30 - h2ip = 5-甲氧基间苯二甲酸，bib = 1,4-双(2-甲基咪唑-1-基)丁烷)，并用元素分析、红外光谱和x射线晶体学对其进行了研究。配合物1在具有空间群p_1的三斜体系中结晶，并呈二维(2-D)(3,4)连接网。此外，对1的热重分析(TGA)和发光性能进行了研究。

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Synthesis, Crystal Structure, and Luminescent Property of One Zinc(II) Complex Based on 5-Methoxyisophthalate Ligand

A new Zn(II) complex, {[Zn2(CH3O-ip)2(bib)]·(H2O)}n (1) (CH3O-H2ip = 5-methoxyisophthalic acid, bib = 1,4-bis(2-methyl-imidazol-1-yl)butane, was synthesized and studied by elemental analysis, IR spectroscopy and X-ray crystallography. Complex 1 crystallizes in triclinic system with space group Pī, and exhibits a two-dimensional (2-D) (3,4)-connected net. In addition, thermal gravimetric analysis (TGA) and luminescent property of 1 were investigated.

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来源期刊

Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry 工程技术-纳米科技

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审稿时长

5 months