反应条件对乙基生物柴油酯含量及表征的影响

Sérgio L. Ferreira, Antônio Moreira dos Santos, G. R. D. Souza, W. Polito
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引用次数: 0

摘要

关于最频繁地使用可再生燃料,存在着许多环境和能源秩序的动机。生物柴油是柴油的可再生替代品之一,在巴西等国的应用日益广泛。在巴西,人们倾向于油料种植,生物柴油似乎是一种环境、能源和社会解决方案。研究了几种条件对碱催化乙基路线生产生物柴油过程的影响。考察了乙醇/油摩尔比、反应时间、反应温度等条件对生物柴油合成的影响。以无水乙醇和KOH为催化剂,反应温度为90℃,乙醇与大豆油的摩尔比为8:1,催化剂浓度为1.0 wt.%,得到了大豆油酯交换反应的最佳条件。此外,可以观察到酯含量随着反应时间的延长和温度的升高而增加。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Influence of the Reaction Conditions on the Ester Content and Characterization of Biodiesel via Ethylic Route
There exist many motivations of environmental and energetic order regarding the most frequent use of renewable fuels. Biodiesel is one of the renewable alternatives to diesel oil, and its application has been increasing in Brazil and other countries. In Brazil, there is a positive propensity towards oleaginous cultivation and biodiesel appears as a proposal for the environmental, energetic, and social solution. The present paper deals with the influence of some conditions on the biodiesel production process via ethylic route using alkaline catalysis. Different reaction conditions, such as ethanol/oil molar ratio, reaction time, and temperature were used in the optimization of the biodiesel synthesis. The optimum conditions for the transesterification of soybean oil with anhydrous ethanol and KOH as a catalyst were obtained at 90°C reaction temperature, 8:1 molar ratio of ethanol to soybean oil and 1.0 wt.% catalyst concentration. Moreover, it is possible to observe that the ester content increases with long reaction times and high temperatures.
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