{"title":"二(2-乙基己基)磷酸在正十二烷中的活度系数","authors":"P.R. Danesi, G.F. Vandegrift","doi":"10.1016/0020-1650(81)80039-6","DOIUrl":null,"url":null,"abstract":"<div><p>The activity coefficients of bis(2-ethylhexyl) phosphoric acid, HDEHP, in n-dodecane in the concentration range 1 × 10<sup>−3</sup> − 1 <span><math><mtext>F</mtext></math></span> have been evaluated from liquid-liquid distribution studies of Eu<sup>+3</sup>, Tm<sup>+3</sup> and Ca<sup>2+</sup>. The deviations from ideality have been interpreted in terms of solute-solute weak interactions, where the interacting solute species is the HDEHP dimer.</p></div>","PeriodicalId":13630,"journal":{"name":"Inorganic and Nuclear Chemistry Letters","volume":null,"pages":null},"PeriodicalIF":0.0000,"publicationDate":"1981-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0020-1650(81)80039-6","citationCount":"45","resultStr":"{\"title\":\"Activity coefficients of bis(2-ethylhexyl) phosphoric acid in n-dodecane\",\"authors\":\"P.R. Danesi, G.F. Vandegrift\",\"doi\":\"10.1016/0020-1650(81)80039-6\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>The activity coefficients of bis(2-ethylhexyl) phosphoric acid, HDEHP, in n-dodecane in the concentration range 1 × 10<sup>−3</sup> − 1 <span><math><mtext>F</mtext></math></span> have been evaluated from liquid-liquid distribution studies of Eu<sup>+3</sup>, Tm<sup>+3</sup> and Ca<sup>2+</sup>. The deviations from ideality have been interpreted in terms of solute-solute weak interactions, where the interacting solute species is the HDEHP dimer.</p></div>\",\"PeriodicalId\":13630,\"journal\":{\"name\":\"Inorganic and Nuclear Chemistry Letters\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1981-01-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://sci-hub-pdf.com/10.1016/0020-1650(81)80039-6\",\"citationCount\":\"45\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Inorganic and Nuclear Chemistry Letters\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/0020165081800396\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Inorganic and Nuclear Chemistry Letters","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/0020165081800396","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Activity coefficients of bis(2-ethylhexyl) phosphoric acid in n-dodecane
The activity coefficients of bis(2-ethylhexyl) phosphoric acid, HDEHP, in n-dodecane in the concentration range 1 × 10−3 − 1 have been evaluated from liquid-liquid distribution studies of Eu+3, Tm+3 and Ca2+. The deviations from ideality have been interpreted in terms of solute-solute weak interactions, where the interacting solute species is the HDEHP dimer.
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