V. Vidal, A. Théolier, J. Thivolle-cazat, J. Basset
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Activation and functionalisation of the C–H bonds of methane and higher alkanes by a silica-supported tantalum hydride complex
Silica-supported tantalum hydride activates at low temperature the C–H and the C–D bonds of cyclooctane and CD4, respectively, to form the corresponding cyclooctyl and perdeuteriomethyl-tantalum surface complexes; these complexes are transformed under molecular oxygen into the corresponding tantalum-alkoxy derivatives which with acetic acid give rise to the corresponding alkylacetates.
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