非线性光学分子平行排列的超分子方法

J. Hulliger, P. Langley, O. Koenig, S. Roth, A. Quintel, P. Rechsteiner
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引用次数: 16

摘要

利用过氢三苯(PHTP)作为包合主体化合物的超分子合成已被证明是一种平行排列客体非线性光学(NLO)分子的有效方法。应用马尔可夫随机过程理论,在宏观上成功地解释了实验观察到的极性自发形成。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
A supramolecular approach to the parallel alignment of nonlinear optical molecules
A supramolecular synthesis utilizing perhydrotriphenylene (PHTP) as an inclusion host compound has proven to be an efficient method of aligning guest nonlinear optical (NLO) molecules in a parallel fashion. Application of Markov's theory of stochastic processes explains successfully the experimentally observed spontaneous formation of polarity on a macroscopic level.
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