Platinum Monolayer Electrocatalysts for the Oxygen Reduction Reaction: Improvements Induced by Surface and Subsurface Modifications of Cores

This paper demonstrates that the ORR activity of PtML electrocatalysts can be further improved by the modification of surface and subsurface of the core materials. The removal of surface low-coordination sites, generation (via addition or segregation) of an interlayer between PtML and the core, or the introduction of a second metal component to the subsurface layer of the core can further improve the ORR activity and/or stability of PtML electrocatalysts. These modifications generate the alternation of the interactions between the substrate and the PtML, involving the changes on both electronic (ligand) and geometric (strain) properties of the substrates. The improvements resulted from the application of these approaches provide a new perspective to designing of the new generation PtML electrocatalysts.