第六章。通过阳离子-π相互作用的铵离子辅助有机反应

S. Yamada
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引用次数: 1

摘要

阳离子-π相互作用是阳离子和π面之间具有吸引力的非共价相互作用。由于阳离子- π相互作用比其他π相互作用(如π - π和CH - π)具有更强的相互作用能,阳离子- π相互作用最近被认为是控制各种类型有机反应的区域选择性和立体选择性的新工具。本章试图涵盖各种由非反应性离子和π面相互作用辅助的有机反应,这将提供有关阳离子-π相互作用在有机合成中的作用的全面知识。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
CHAPTER 6. Onium Ion-assisted Organic Reactions Through Cation–π Interactions
The cation–π interaction is an attractive noncovalent interaction between a cation and a π-face. Owing to the stronger interaction energy than those of the other π interactions, such as π–π and CH–π interactions, the cation–π interaction has recently been recognized as a new tool for controlling the regio- and stereoselectivities in various types of organic reactions. This chapter attempts to cover a variety of organic reactions assisted by interactions between unreactive onium ions and π-faces, which will provide comprehensive knowledge on the role of cation–π interactions in organic synthesis.
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