理解布格-比尔-朗伯定律的极限

IF 0.8 4区化学 Q4 SPECTROSCOPY

Spectroscopy Pub Date : 2023-08-01 DOI:10.56530/spectroscopy.iq2368r9

T. Mayerhöfer, S. Pahlow, Juergen Popp

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引用次数: 0

摘要

布格-比尔-朗伯定律经常应用于光谱学和分光光度法。通常假设它准确地描述了由光-物质相互作用引起的观察到的变化，并正确地反映了起作用的物理现象。然而，在大多数情况下，这是不正确的，当不加批判地应用布格-比尔-朗伯定律时，问题就会出现。在这篇简短的文章中，我们将评论它的基本限制及其物理背景。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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Understanding the Limits of the Bouguer-Beer-Lambert Law

The Bouguer-Beer-Lambert law is frequently applied in spectroscopy and spectrophotometry. Often it is assumed that it accurately describes the observed changes induced by light-matter interactions and properly reflects the physical phenomena at play. For most cases, however, this is not true, and issues can arise when the Bouguer-Beer-Lambert law is applied uncritically. In this short article, we will comment on its fundamental limits and their physical background.

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来源期刊

Spectroscopy 物理-光谱学

CiteScore

1.10

自引率

0.00%

发文量

审稿时长

3 months

期刊介绍： Spectroscopy welcomes manuscripts that describe techniques and applications of all forms of spectroscopy and that are of immediate interest to users in industry, academia, and government.