基于再生聚乳酸(R-PLA)/再生聚碳酸酯(R-PC)和不同长径比纤维素纤维的反应性挤出生物复合材料的力学响应

Macromol Pub Date : 2022-10-26 DOI:10.3390/macromol2040032
V. Gigante, Laura Aliotta, M. Coltelli, A. Lazzeri
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引用次数: 0

摘要

将回收过程与生物衍生和环境友好材料的增加使用结合起来,目的是接近(或克服)石油衍生塑料的机械性能,这是一条研究正在追求的小而重要的步骤。正是在这一流程中,本文希望适合于开发从热成型加工废料中获得的再生聚乳酸(R-PLA)/再生聚碳酸酯(R-PC)共混物,并用具有三种不同长宽比的纤维素纤维增强它们。目的是了解“二次寿命”材料的机械性能,它们对一些微力学预测模型的粘附性,以及这些天然纤维与其尺寸相关的增强能力。此外,在挤压过程中加入了一种基于三乙酸酯(TA)和四苯基硼酸四丁基铵(TBATPB)的增容体系,以研究R-PLA/R-PC与纤维素纤维之间是否能发生反应。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Mechanical Response of Reactive Extruded Biocomposites Based on Recycled Poly(lactic Acid) (R-PLA)/Recycled Polycarbonate (R-PC) and Cellulosic Fibers with Different Aspect Ratios
Coupling recycling processes with increased use of bio-derived and environmentally friendly materials, with the aim of approaching (or overcoming) the mechanical properties of petroleum-derived plastics, is a path that research is pursuing in small but important steps. It is in this stream that this paper wants to fit in developing recycled poly(lactic acid) (R-PLA)/recycled polycarbonate (R-PC) blends obtained from thermoforming processing scraps and reinforcing them with cellulosic-derived fibers, having three different aspect ratios. The aim is to understand the mechanical properties of “second life” materials, their adherence to some micromechanical predictive models and the reinforcement capacity of these natural fibers in relation to their dimensions. Moreover, a compatibilizing system, based on Triacetin (TA) and Tetrabutylammonium Tetraphenylborate (TBATPB), has been added during the extrusion to investigate if a reactive process among R-PLA/R-PC and cellulosic fibers can be achieved.
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CiteScore
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