V. Gigante, Laura Aliotta, M. Coltelli, A. Lazzeri
{"title":"基于再生聚乳酸(R-PLA)/再生聚碳酸酯(R-PC)和不同长径比纤维素纤维的反应性挤出生物复合材料的力学响应","authors":"V. Gigante, Laura Aliotta, M. Coltelli, A. Lazzeri","doi":"10.3390/macromol2040032","DOIUrl":null,"url":null,"abstract":"Coupling recycling processes with increased use of bio-derived and environmentally friendly materials, with the aim of approaching (or overcoming) the mechanical properties of petroleum-derived plastics, is a path that research is pursuing in small but important steps. It is in this stream that this paper wants to fit in developing recycled poly(lactic acid) (R-PLA)/recycled polycarbonate (R-PC) blends obtained from thermoforming processing scraps and reinforcing them with cellulosic-derived fibers, having three different aspect ratios. The aim is to understand the mechanical properties of “second life” materials, their adherence to some micromechanical predictive models and the reinforcement capacity of these natural fibers in relation to their dimensions. Moreover, a compatibilizing system, based on Triacetin (TA) and Tetrabutylammonium Tetraphenylborate (TBATPB), has been added during the extrusion to investigate if a reactive process among R-PLA/R-PC and cellulosic fibers can be achieved.","PeriodicalId":18139,"journal":{"name":"Macromol","volume":"23 1","pages":""},"PeriodicalIF":0.0000,"publicationDate":"2022-10-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Mechanical Response of Reactive Extruded Biocomposites Based on Recycled Poly(lactic Acid) (R-PLA)/Recycled Polycarbonate (R-PC) and Cellulosic Fibers with Different Aspect Ratios\",\"authors\":\"V. Gigante, Laura Aliotta, M. Coltelli, A. Lazzeri\",\"doi\":\"10.3390/macromol2040032\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Coupling recycling processes with increased use of bio-derived and environmentally friendly materials, with the aim of approaching (or overcoming) the mechanical properties of petroleum-derived plastics, is a path that research is pursuing in small but important steps. It is in this stream that this paper wants to fit in developing recycled poly(lactic acid) (R-PLA)/recycled polycarbonate (R-PC) blends obtained from thermoforming processing scraps and reinforcing them with cellulosic-derived fibers, having three different aspect ratios. The aim is to understand the mechanical properties of “second life” materials, their adherence to some micromechanical predictive models and the reinforcement capacity of these natural fibers in relation to their dimensions. Moreover, a compatibilizing system, based on Triacetin (TA) and Tetrabutylammonium Tetraphenylborate (TBATPB), has been added during the extrusion to investigate if a reactive process among R-PLA/R-PC and cellulosic fibers can be achieved.\",\"PeriodicalId\":18139,\"journal\":{\"name\":\"Macromol\",\"volume\":\"23 1\",\"pages\":\"\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2022-10-26\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Macromol\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.3390/macromol2040032\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Macromol","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.3390/macromol2040032","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Mechanical Response of Reactive Extruded Biocomposites Based on Recycled Poly(lactic Acid) (R-PLA)/Recycled Polycarbonate (R-PC) and Cellulosic Fibers with Different Aspect Ratios
Coupling recycling processes with increased use of bio-derived and environmentally friendly materials, with the aim of approaching (or overcoming) the mechanical properties of petroleum-derived plastics, is a path that research is pursuing in small but important steps. It is in this stream that this paper wants to fit in developing recycled poly(lactic acid) (R-PLA)/recycled polycarbonate (R-PC) blends obtained from thermoforming processing scraps and reinforcing them with cellulosic-derived fibers, having three different aspect ratios. The aim is to understand the mechanical properties of “second life” materials, their adherence to some micromechanical predictive models and the reinforcement capacity of these natural fibers in relation to their dimensions. Moreover, a compatibilizing system, based on Triacetin (TA) and Tetrabutylammonium Tetraphenylborate (TBATPB), has been added during the extrusion to investigate if a reactive process among R-PLA/R-PC and cellulosic fibers can be achieved.