{"title":"六族金属卡宾配合物作为烯烃歧化催化剂的研究","authors":"W. Kroll, G. Doyle","doi":"10.1039/C29710000839","DOIUrl":null,"url":null,"abstract":"Group VI metal carbene complexes of the type NR4[M(CO)5COR′] can be activated with alkyl-aluminium halides to give catalysts which disproportionate not only non-terminal olefins but also terminal olefins.","PeriodicalId":17278,"journal":{"name":"Journal of The Chemical Society D: Chemical Communications","volume":"6 1","pages":"839-839"},"PeriodicalIF":0.0000,"publicationDate":"1971-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"9","resultStr":"{\"title\":\"Carbene complexes of the group VI metals as olefin disproportionation catalysts\",\"authors\":\"W. Kroll, G. Doyle\",\"doi\":\"10.1039/C29710000839\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Group VI metal carbene complexes of the type NR4[M(CO)5COR′] can be activated with alkyl-aluminium halides to give catalysts which disproportionate not only non-terminal olefins but also terminal olefins.\",\"PeriodicalId\":17278,\"journal\":{\"name\":\"Journal of The Chemical Society D: Chemical Communications\",\"volume\":\"6 1\",\"pages\":\"839-839\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1971-01-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"9\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of The Chemical Society D: Chemical Communications\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1039/C29710000839\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of The Chemical Society D: Chemical Communications","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1039/C29710000839","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Carbene complexes of the group VI metals as olefin disproportionation catalysts
Group VI metal carbene complexes of the type NR4[M(CO)5COR′] can be activated with alkyl-aluminium halides to give catalysts which disproportionate not only non-terminal olefins but also terminal olefins.