{"title":"具有不同数量碗状基团的半羧酸内相客体逸出活化能的比较","authors":"Timothy A. Bobbins, D. Cram","doi":"10.1039/C39950001515","DOIUrl":null,"url":null,"abstract":"The syntheses and characterization of new hemicarcerands 3 and new complexes of 4 are described; the half-lives and activation energies for incarcerated Me2NCHO and Me2NCOMe escaping from the inner phases of 2 and 4 are compared.","PeriodicalId":17282,"journal":{"name":"Journal of The Chemical Society, Chemical Communications","volume":null,"pages":null},"PeriodicalIF":0.0000,"publicationDate":"1995-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"8","resultStr":"{\"title\":\"Comparisons of activation energies for guest escapes from the inner phases of hemicarcerands with varying numbers of bowl-linking groups\",\"authors\":\"Timothy A. Bobbins, D. Cram\",\"doi\":\"10.1039/C39950001515\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"The syntheses and characterization of new hemicarcerands 3 and new complexes of 4 are described; the half-lives and activation energies for incarcerated Me2NCHO and Me2NCOMe escaping from the inner phases of 2 and 4 are compared.\",\"PeriodicalId\":17282,\"journal\":{\"name\":\"Journal of The Chemical Society, Chemical Communications\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1995-01-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"8\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of The Chemical Society, Chemical Communications\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1039/C39950001515\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of The Chemical Society, Chemical Communications","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1039/C39950001515","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Comparisons of activation energies for guest escapes from the inner phases of hemicarcerands with varying numbers of bowl-linking groups
The syntheses and characterization of new hemicarcerands 3 and new complexes of 4 are described; the half-lives and activation energies for incarcerated Me2NCHO and Me2NCOMe escaping from the inner phases of 2 and 4 are compared.
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