{"title":"含P、N、O给体的新型三叉配体钌(II)配合物:丙二醇转移加氢酮的高效催化剂","authors":"Hong Yang, M. Alvarez, N. Lugan, R. Mathieu","doi":"10.1039/C39950001721","DOIUrl":null,"url":null,"abstract":"The complexes [RuCl2(PPh3)(L)] in which L is a tridentate ligand with P, N and O donor atoms are very efficient catalysts for the transfer hydrogenation of cyclic ketones and acetophenone (turnover ⩽ 118 800 h–1) in basic media; when L is optically active, no significant e.e. is observed.","PeriodicalId":17282,"journal":{"name":"Journal of The Chemical Society, Chemical Communications","volume":"6 1","pages":"1721-1722"},"PeriodicalIF":0.0000,"publicationDate":"1995-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"64","resultStr":"{\"title\":\"Ruthenium(II) complexes with new tridentate ligands containing P, N, O donor atoms: highly efficient catalysts for transfer hydrogenation of ketones by propan-2-ol\",\"authors\":\"Hong Yang, M. Alvarez, N. Lugan, R. Mathieu\",\"doi\":\"10.1039/C39950001721\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"The complexes [RuCl2(PPh3)(L)] in which L is a tridentate ligand with P, N and O donor atoms are very efficient catalysts for the transfer hydrogenation of cyclic ketones and acetophenone (turnover ⩽ 118 800 h–1) in basic media; when L is optically active, no significant e.e. is observed.\",\"PeriodicalId\":17282,\"journal\":{\"name\":\"Journal of The Chemical Society, Chemical Communications\",\"volume\":\"6 1\",\"pages\":\"1721-1722\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1995-01-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"64\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of The Chemical Society, Chemical Communications\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1039/C39950001721\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of The Chemical Society, Chemical Communications","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1039/C39950001721","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Ruthenium(II) complexes with new tridentate ligands containing P, N, O donor atoms: highly efficient catalysts for transfer hydrogenation of ketones by propan-2-ol
The complexes [RuCl2(PPh3)(L)] in which L is a tridentate ligand with P, N and O donor atoms are very efficient catalysts for the transfer hydrogenation of cyclic ketones and acetophenone (turnover ⩽ 118 800 h–1) in basic media; when L is optically active, no significant e.e. is observed.
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