{"title":"含二(二苯基硫代膦基)甲烷的离子Pt(II)配合物","authors":"S. Irişli, Leman Alkan","doi":"10.1081/SIM-200030224","DOIUrl":null,"url":null,"abstract":"Abstract In this study, dipositive platinum(II) complexes of the general formula [Pt(L–L)(dppmS2)](ClO4)2, where dppmS2 = Ph2P(S)CH2P(S)Ph2 and L–L = dppm (Ph2PCH2PPh2), dppe (Ph2PCH2CH2PPh2), and dppp (Ph2PCH2CH2CH2PPh2), have been synthesized and characterized by 31P{1H} NMR, 13C NMR, IR spectra and elemental analyses.","PeriodicalId":22160,"journal":{"name":"Synthesis and Reactivity in Inorganic and Metal-organic Chemistry","volume":null,"pages":null},"PeriodicalIF":0.0000,"publicationDate":"2004-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"3","resultStr":"{\"title\":\"Ionic Pt(II) Complexes Containing bis(Diphenylthiophosphinyl)methane\",\"authors\":\"S. Irişli, Leman Alkan\",\"doi\":\"10.1081/SIM-200030224\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Abstract In this study, dipositive platinum(II) complexes of the general formula [Pt(L–L)(dppmS2)](ClO4)2, where dppmS2 = Ph2P(S)CH2P(S)Ph2 and L–L = dppm (Ph2PCH2PPh2), dppe (Ph2PCH2CH2PPh2), and dppp (Ph2PCH2CH2CH2PPh2), have been synthesized and characterized by 31P{1H} NMR, 13C NMR, IR spectra and elemental analyses.\",\"PeriodicalId\":22160,\"journal\":{\"name\":\"Synthesis and Reactivity in Inorganic and Metal-organic Chemistry\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2004-12-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"3\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Synthesis and Reactivity in Inorganic and Metal-organic Chemistry\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1081/SIM-200030224\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Synthesis and Reactivity in Inorganic and Metal-organic Chemistry","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1081/SIM-200030224","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Abstract In this study, dipositive platinum(II) complexes of the general formula [Pt(L–L)(dppmS2)](ClO4)2, where dppmS2 = Ph2P(S)CH2P(S)Ph2 and L–L = dppm (Ph2PCH2PPh2), dppe (Ph2PCH2CH2PPh2), and dppp (Ph2PCH2CH2CH2PPh2), have been synthesized and characterized by 31P{1H} NMR, 13C NMR, IR spectra and elemental analyses.