{"title":"具有无穷多个耦合化学反应的模型的松弛谱的显式表达式","authors":"O.J. Heilmann","doi":"10.1016/0001-8716(76)80017-X","DOIUrl":null,"url":null,"abstract":"<div><p>The explicit expression for the relaxation spectrum of the polymerization reaction <em>A</em><sub>1</sub> + <em>A<sub>n</sub></em> ⇌ <em>A</em><sub><em>n</em>+1</sub> (<em>n</em> 1, 2, …) where all reactions are supposed to have the same values of the thermodynamic and kinetic parameters, is given. The result deviates significantly from what would be predicted if the reactions were considered to be independent.</p></div>","PeriodicalId":100050,"journal":{"name":"Advances in Molecular Relaxation Processes","volume":"8 2","pages":"Pages 155-168"},"PeriodicalIF":0.0000,"publicationDate":"1976-05-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0001-8716(76)80017-X","citationCount":"2","resultStr":"{\"title\":\"Explicit expression for the relaxation spectrum of a model with infinitely many coupled chemical reactions\",\"authors\":\"O.J. Heilmann\",\"doi\":\"10.1016/0001-8716(76)80017-X\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>The explicit expression for the relaxation spectrum of the polymerization reaction <em>A</em><sub>1</sub> + <em>A<sub>n</sub></em> ⇌ <em>A</em><sub><em>n</em>+1</sub> (<em>n</em> 1, 2, …) where all reactions are supposed to have the same values of the thermodynamic and kinetic parameters, is given. The result deviates significantly from what would be predicted if the reactions were considered to be independent.</p></div>\",\"PeriodicalId\":100050,\"journal\":{\"name\":\"Advances in Molecular Relaxation Processes\",\"volume\":\"8 2\",\"pages\":\"Pages 155-168\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1976-05-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://sci-hub-pdf.com/10.1016/0001-8716(76)80017-X\",\"citationCount\":\"2\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Advances in Molecular Relaxation Processes\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/000187167680017X\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Advances in Molecular Relaxation Processes","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/000187167680017X","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Explicit expression for the relaxation spectrum of a model with infinitely many coupled chemical reactions
The explicit expression for the relaxation spectrum of the polymerization reaction A1 + An ⇌ An+1 (n 1, 2, …) where all reactions are supposed to have the same values of the thermodynamic and kinetic parameters, is given. The result deviates significantly from what would be predicted if the reactions were considered to be independent.
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