几种非常规化学方法在双环二聚甲醛甲酯合成中的应用

IF 0.5 Q4 CHEMISTRY, MULTIDISCIPLINARY

Chemistry Journal of Moldova Pub Date : 2020-12-01 DOI:10.19261/cjm.2020.791

A. Ciocarlan, L. Lungu, S. Blaja, I. Dragalin, A. Aricu

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引用次数: 3

摘要

本文报道了微波辅助法制备双环同源芳二烯甲酯的实验结果，并与传统的斯托尔法和辛德法进行了比较。此外，还通过阳极电氧化和染料敏化光氧化进行了双环同型二芳二烯甲酯的化学转化。介绍了一种制备甲基7-氧-13,14,15,16-四异丙基-6,8(8)-二烯-12-oate的新方法及其电化学产物的生成机理。所有合成化合物的结构都通过光谱方法得到了充分的证实。

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The Use of Some Non-conventional Methods in Chemistry of Bicyclohomofarnesenic Methyl Esters

The present paper reports the results of microwave irradiation assisted method for the preparation of bicyclohomofarnesenic methyl esters versus classical Stoll and Hinder method. Moreover, the chemical transformations of bicyclohomofarnesenic methyl esters via anodic electrooxidation and dye-sensitized photooxidation were performed. A new method for the preparation of methyl 7-oxo-13,14,15,16-tetranorlabd-6,8(8)-dien-12-oate and the mechanism of electrochemical products formation are presented. The structure of all synthesized compounds was fully confirmed by spectral methods.

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来源期刊

Chemistry Journal of Moldova CHEMISTRY, MULTIDISCIPLINARY-

CiteScore

0.90

自引率

20.00%

发文量

审稿时长

12 weeks

期刊介绍： "Chemistry Journal of Moldova. General, Industrial and Ecological Chemistry" seeks to publish experimental or theoretical research results of outstanding significance and timeliness in all fields of Chemistry, including Industrial and Ecological Chemistry. The main goal of this edition is strengthening the Chemical Society of Moldova, following development of research in Moldovan chemical institutions and promotion of their collaboration with international chemical community. Manuscripts are welcome from all countries.