{"title":"Tl2[(S0.6Se0.4)O4]Te(OH)6的合成与晶体结构","authors":"M. Abdelhedi, M. Dammak, A. Kolsi, A. Cousson","doi":"10.2116/ANALSCIX.24.X93","DOIUrl":null,"url":null,"abstract":"The crystal structure of the thallium sulfate selenate tellurate Tl2[(S0.6Se0.4)O4]Te(OH)6 was determined with single-crystal X-ray diffraction data. The title compound crystallizes in the monoclinic system with the P21/c space group. The unit-cell dimensions at 298 K are a = 12.3580(10)A, b = 7.2310(10)A, c = 11.9860(10)A, β = 111.090(10)°, V = 999.33(19)A3, Dx = 5.029 g/cm3, and Z = 4. The R value is 0.047 for 1799 reflections. The anions are disposed in a number of sheets of pure (S,Se)O4 tetrahedra, alterning with sheets of pure Te(OH)6 octahedra. All of those planes are intercalated in a bidimensional arrangement by Tl+ cations.","PeriodicalId":7796,"journal":{"name":"Analytical Sciences: X-ray Structure Analysis Online","volume":"1 1","pages":""},"PeriodicalIF":0.0000,"publicationDate":"2008-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"4","resultStr":"{\"title\":\"Synthesis and Crystal Structure of Tl2[(S0.6Se0.4)O4]Te(OH)6\",\"authors\":\"M. Abdelhedi, M. Dammak, A. Kolsi, A. Cousson\",\"doi\":\"10.2116/ANALSCIX.24.X93\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"The crystal structure of the thallium sulfate selenate tellurate Tl2[(S0.6Se0.4)O4]Te(OH)6 was determined with single-crystal X-ray diffraction data. The title compound crystallizes in the monoclinic system with the P21/c space group. The unit-cell dimensions at 298 K are a = 12.3580(10)A, b = 7.2310(10)A, c = 11.9860(10)A, β = 111.090(10)°, V = 999.33(19)A3, Dx = 5.029 g/cm3, and Z = 4. The R value is 0.047 for 1799 reflections. The anions are disposed in a number of sheets of pure (S,Se)O4 tetrahedra, alterning with sheets of pure Te(OH)6 octahedra. All of those planes are intercalated in a bidimensional arrangement by Tl+ cations.\",\"PeriodicalId\":7796,\"journal\":{\"name\":\"Analytical Sciences: X-ray Structure Analysis Online\",\"volume\":\"1 1\",\"pages\":\"\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2008-01-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"4\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Analytical Sciences: X-ray Structure Analysis Online\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.2116/ANALSCIX.24.X93\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Analytical Sciences: X-ray Structure Analysis Online","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.2116/ANALSCIX.24.X93","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 4
摘要
用单晶x射线衍射测定了硫酸硒酸碲铊Tl2[(S0.6Se0.4)O4]Te(OH)6的晶体结构。标题化合物在具有P21/c空间基团的单斜晶系中结晶。298 K时的晶胞尺寸为a = 12.3580(10) a, b = 7.2310(10) a, c = 11.9860(10) a， β = 111.090(10)°，V = 999.33(19)A3, Dx = 5.029 g/cm3, Z = 4。1799次反射的R值为0.047。阴离子被放置在许多片的纯(S,Se)O4四面体中，与片的纯Te(OH)6八面体交替。所有这些平面都是由Tl+阳离子以二维排列插入的。
Synthesis and Crystal Structure of Tl2[(S0.6Se0.4)O4]Te(OH)6
The crystal structure of the thallium sulfate selenate tellurate Tl2[(S0.6Se0.4)O4]Te(OH)6 was determined with single-crystal X-ray diffraction data. The title compound crystallizes in the monoclinic system with the P21/c space group. The unit-cell dimensions at 298 K are a = 12.3580(10)A, b = 7.2310(10)A, c = 11.9860(10)A, β = 111.090(10)°, V = 999.33(19)A3, Dx = 5.029 g/cm3, and Z = 4. The R value is 0.047 for 1799 reflections. The anions are disposed in a number of sheets of pure (S,Se)O4 tetrahedra, alterning with sheets of pure Te(OH)6 octahedra. All of those planes are intercalated in a bidimensional arrangement by Tl+ cations.
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