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IF 2.1 4区化学 Q3 CHEMISTRY, MULTIDISCIPLINARY

Supramolecular Chemistry Pub Date : 2021-08-03 DOI:10.1080/10610278.2022.2039653

Yang Chao, A. C. Sue

引用次数: 4

摘要

本文报道了从不对称取代柱[6]芳烃中间体的异构体混合物中成功合成并分离出冠[6]芳烃，冠[6]芳烃是杯[6]芳烃的组成异构体，由六个由对取代亚甲基桥连接的酚单元组成。与其五聚体类似物一样，tiara[6]芳烃在溶液中具有很高的构象自由度，在固态中具有丰富的多态性。冠[n]芳烃族(n = 5和6)的建立进一步扩大了大环化学的范围。图形抽象

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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Tiara[6]arenes

ABSTRACT Herein we report the successful synthesis and isolation of tiara[6]arene, a constitutional isomer of calix[6]arene consisting of six phenol units linked by para-substituted methylene bridges, from an isomeric mixture of asymmetrically substituted pillar[6]arene intermediates. Similar to its pentameric analogue, tiara[6]arene displays high conformational freedom in solution and rich polymorphism in the solid state. The establishment of the tiara[n]arene family (n = 5 and 6) further expands the scope of macrocyclic chemistry. Graphical Abstract

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来源期刊

Supramolecular Chemistry 化学-化学综合

CiteScore

3.60

自引率

3.00%

发文量

审稿时长

2.7 months

期刊介绍： Supramolecular Chemistry welcomes manuscripts from the fields and sub-disciplines related to supramolecular chemistry and non-covalent interactions. From host-guest chemistry, self-assembly and systems chemistry, through materials chemistry and biochemical systems, we interpret supramolecular chemistry in the broadest possible sense. Interdisciplinary manuscripts are particularly encouraged. Manuscript types include: high priority communications; full papers; reviews, and; Methods papers, techniques tutorials highlighting procedures and technologies that are important to the field. We aim to publish papers in a timely fashion and as soon as a paper has been accepted and typeset it will be published in electronic form on the Latest articles section of the website. The two most important review criteria are that the paper presents high-quality work that fits generally into the broad spectrum of activities in the supramolecular chemistry field. Under normal circumstances, Supramolecular Chemistry does not consider manuscripts that would be more suitable in a highly specialized journal. This includes, but is not limited to, those based mostly or exclusively on topics such as solid state/X-ray structures, computational chemistry, or electrochemistry. . The two most important review criteria are that the paper presents high-quality work that fits generally into the broad spectrum of activities in the supramolecular chemistry field.