利用甲基自由基†的快速电化学方法回收碳纤维复合材料

IF 9.3 1区化学 Q1 CHEMISTRY, MULTIDISCIPLINARY

Green Chemistry Pub Date : 2023-09-18 DOI:10.1039/d3gc01765f

Zehan Yu , Y. Justin Lim , Travis Williams , Steven Nutt

引用次数: 0

摘要

介绍了一种用电化学方法从胺环氧碳纤维增强聚合物(CFRPs)中回收碳纤维(CF)织物的方法。我们的新方法利用类似科尔贝的机制，从CH3COOH产生甲基自由基，通过氢原子抽象来切割环氧基中的C-N键。回收的碳纤维然后再制造成碳纤维碳纤维而不调整大小。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

A rapid electrochemical method to recycle carbon fiber composites using methyl radicals†

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A rapid electrochemical method to recycle carbon fiber composites using methyl radicals†

We introduce an electrochemical approach to recycle carbon fiber (CF) fabrics from amine-epoxy carbon fiber-reinforced polymers (CFRPs). Our novel method utilizes a Kolbe-like mechanism to generate methyl radicals from CH₃COOH to cleave C–N bonds within epoxy matrices via hydrogen atom abstraction. Recovered CFs are then remanufactured into CFRPs without resizing.

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来源期刊

Green Chemistry 化学-化学综合

CiteScore

16.10

自引率

7.10%

发文量

677

审稿时长

1.4 months

期刊介绍： Green Chemistry is a journal that provides a unique forum for the publication of innovative research on the development of alternative green and sustainable technologies. The scope of Green Chemistry is based on the definition proposed by Anastas and Warner (Green Chemistry: Theory and Practice, P T Anastas and J C Warner, Oxford University Press, Oxford, 1998), which defines green chemistry as the utilisation of a set of principles that reduces or eliminates the use or generation of hazardous substances in the design, manufacture and application of chemical products. Green Chemistry aims to reduce the environmental impact of the chemical enterprise by developing a technology base that is inherently non-toxic to living things and the environment. The journal welcomes submissions on all aspects of research relating to this endeavor and publishes original and significant cutting-edge research that is likely to be of wide general appeal. For a work to be published, it must present a significant advance in green chemistry, including a comparison with existing methods and a demonstration of advantages over those methods.