O. Pavlova, A. Litvinovich, A. Lavrishchev, A. Belimov, E. Saljnikov
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引用次数: 2
摘要
对工业废弃物再生的钠灰化土进行了室内柱实验,研究了有机-矿物络合物(OMC)在洗涤过程中迁移的组成。在pH值为13时,OMC中的碳析出量在5.5 ~ 5.7%之间,与应用的改进剂颗粒大小无关。OMC溶液的光密度(Есg ml -1)为2.7 ~ 3.1,在典型的黄腐酸范围内。从OMC中冲刷出的Ca、Mg、Sr的总量取决于改性颗粒的大小,以及其中碱土金属的含量和比例。粒径越小,Ca、Mg、Sr的迁移损失越大。改良剂中大量Mg的存在增加了碱的非生产性损失。根据在OMC中的迁移能力,所研究的元素可以按以下降序排列:Mg> Ca> sr。出乎意料的是,新发现并不是所有在再生钠灰化土中迁移的有机物都能在介质的强碱性反应条件下沉淀。
Composition of organo-mineral complexes migrating in soddy-podzolic soil (Umbric Albeluvisols Abruptic)
In laboratory column experiments carried out on soddy-podzolic soil reclaimed by industry wastes, the composition of organo-mineral complexes (OMC) migrating during the washing was studied. Carbon from OMC precipitated at pH 13, and ranged from 5.5 to 5.7%, regardless of the particlesizes of applied ameliorant. The optical density (Есg ml -1 ) of OMC solution was 2.7 to 3.1, which is within the range typical forfulvic acids. The total amount of Ca, Mg, Sr washed out from the OMC depended on the size of the ameliorant particles, as well as the content and ratio of alkaline earth metals in it. The smaller the particle size was, the migration losses of Ca, Mg, Sr were higher. The presence of significant amounts of Mg in the ameliorant enhances unproductive loss of the bases. According to the ability to migrate in the OMC, the studied elements can be arranged in the following descending order: Mg> Ca> Sr. Unexpectedly new finding was that not all organic substances migrating in the profile of reclaimed soddy-podzolic soils can precipitate under the conditions of a strongly alkaline reaction of the medium.