路易斯酸AlCl3氯化醇的简便新途径

有机化学国际期刊(英文) Pub Date : 2012-03-15 DOI:10.4236/IJOC.2012.21004

Hengchang Ma, Zhikang Bao, Li-Jie Bai, W. Cao

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引用次数: 5

摘要

介绍了卤化铝酸盐AlCl3作为取代醇羟基的高效氯化试剂。伯、仲苯醇均可转化为相应的芳香族卤化物，转化几乎完全，具有独特的选择性。作为氯化试剂，AlCl3具有材料成本低、可商品化、产品分离方便等无可比拟的优势。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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A New Facile Route to Chlorination of Alcohols via Lewis Acid AlCl3

Halogenated aluminates AlCl3, applied as efficient chlorination reagent for hydroxyl groups of substitution alcohols is described. Primary and secondary benzylic alcohols could be transformed into corresponding aromatic halides with almost complete conversion and unique selectivity. As chlorination reagent, AlCl3 has an incomparable advantage over others, such as low material cost, commercial availability as well as convenient product isolation.

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来源期刊

有机化学国际期刊(英文)

自引率

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发文量

297