一种快速检测农药残留的光谱分析方法

IF 0.6 4区 化学 Q4 CHEMISTRY, MULTIDISCIPLINARY
Jing Huang Jing Huang, Jincan Lei Jincan Lei, Shixian Zhao and Yan Li Shixian Zhao and Yan Li
{"title":"一种快速检测农药残留的光谱分析方法","authors":"Jing Huang Jing Huang, Jincan Lei Jincan Lei, Shixian Zhao and Yan Li Shixian Zhao and Yan Li","doi":"10.52568/001189/jcsp/44.06.2022","DOIUrl":null,"url":null,"abstract":"In this paper, a fast detection method for pesticide residues was proposed, and the qualitative and quantitative detection of the pesticide could be got at once by the method of solution of multiple linear regression equations which were obtained by dual wavelength absorbance and fluorescence spectrometry with least squares method. Moreover, it could detect two kinds of mixed pesticides. Four selected pesticides, aldicarb, fenitrothion, fenvalerate, and chlorothalonil were detected by the method. The results shown that there were good linear relationship in the range of 0.01-1 ppm, and R2 > 0.90. And the method could 100% discriminate the four pesticide residues, the limit of detection was below 8 ppb both single one and mixed one. The recoveries of the pesticides in cabbage samples were observed 92.12%-107.50%. And the recoveries of the mixed pesticides in mineral water samples were observed 86.44%-114.10%. The preliminary study demonstrates that the proposed method has excellent potential application for the safety inspection of food.","PeriodicalId":17253,"journal":{"name":"Journal of the chemical society of pakistan","volume":null,"pages":null},"PeriodicalIF":0.6000,"publicationDate":"2022-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"1","resultStr":"{\"title\":\"A Fast Detection Method for Pesticide Residues by Spectrometry Technique\",\"authors\":\"Jing Huang Jing Huang, Jincan Lei Jincan Lei, Shixian Zhao and Yan Li Shixian Zhao and Yan Li\",\"doi\":\"10.52568/001189/jcsp/44.06.2022\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"In this paper, a fast detection method for pesticide residues was proposed, and the qualitative and quantitative detection of the pesticide could be got at once by the method of solution of multiple linear regression equations which were obtained by dual wavelength absorbance and fluorescence spectrometry with least squares method. Moreover, it could detect two kinds of mixed pesticides. Four selected pesticides, aldicarb, fenitrothion, fenvalerate, and chlorothalonil were detected by the method. The results shown that there were good linear relationship in the range of 0.01-1 ppm, and R2 > 0.90. And the method could 100% discriminate the four pesticide residues, the limit of detection was below 8 ppb both single one and mixed one. The recoveries of the pesticides in cabbage samples were observed 92.12%-107.50%. And the recoveries of the mixed pesticides in mineral water samples were observed 86.44%-114.10%. The preliminary study demonstrates that the proposed method has excellent potential application for the safety inspection of food.\",\"PeriodicalId\":17253,\"journal\":{\"name\":\"Journal of the chemical society of pakistan\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":0.6000,\"publicationDate\":\"2022-01-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"1\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of the chemical society of pakistan\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://doi.org/10.52568/001189/jcsp/44.06.2022\",\"RegionNum\":4,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of the chemical society of pakistan","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.52568/001189/jcsp/44.06.2022","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 1

摘要

本文提出了一种农药残留快速检测方法,利用最小二乘法对双波长吸光度法和荧光光谱法得到的多元线性回归方程进行求解,即可实现农药残留的定性和定量检测。此外,它还可以检测两种混合农药。采用该方法对四种农药进行了检测,分别为灭虫威、杀虫磷、氰戊酸和百菌清。结果表明,在0.01 ~ 1 ppm范围内,R2 > 0.90呈良好的线性关系。该方法对4种农药残留的检出率均为100%,单残留和混合残留的检出限均在8 ppb以下。白菜样品中农药的回收率为92.12% ~ 107.50%。混合农药在矿泉水样品中的回收率为86.44% ~ 114.10%。初步研究表明,该方法在食品安全检测中具有良好的应用前景。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
A Fast Detection Method for Pesticide Residues by Spectrometry Technique
In this paper, a fast detection method for pesticide residues was proposed, and the qualitative and quantitative detection of the pesticide could be got at once by the method of solution of multiple linear regression equations which were obtained by dual wavelength absorbance and fluorescence spectrometry with least squares method. Moreover, it could detect two kinds of mixed pesticides. Four selected pesticides, aldicarb, fenitrothion, fenvalerate, and chlorothalonil were detected by the method. The results shown that there were good linear relationship in the range of 0.01-1 ppm, and R2 > 0.90. And the method could 100% discriminate the four pesticide residues, the limit of detection was below 8 ppb both single one and mixed one. The recoveries of the pesticides in cabbage samples were observed 92.12%-107.50%. And the recoveries of the mixed pesticides in mineral water samples were observed 86.44%-114.10%. The preliminary study demonstrates that the proposed method has excellent potential application for the safety inspection of food.
求助全文
通过发布文献求助,成功后即可免费获取论文全文。 去求助
来源期刊
CiteScore
1.30
自引率
14.30%
发文量
41
审稿时长
3.4 months
期刊介绍: This journal covers different research areas in the field of Chemistry. These include; Analytical Chemistry, Applied Chemistry, Biochemistry, Environmental Chemistry, Industrial Chemistry, Inorganic Chemistry, Organic Chemistry and Physical Chemistry. The journal publishes full length articles and Reviews from researchers in academia in addition to featuring comments. Chemical Research presents short, concise and critical articles offering easy-to-read overviews of basic research and applications in all areas of chemistry.
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
确定
请完成安全验证×
copy
已复制链接
快去分享给好友吧!
我知道了
右上角分享
点击右上角分享
0
联系我们:info@booksci.cn Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。 Copyright © 2023 布克学术 All rights reserved.
京ICP备2023020795号-1
ghs 京公网安备 11010802042870号
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术官方微信