Xuange Zhang, Tianyu Lu, Yan Cai, Zihong Yan, Zhiwei Miao
{"title":"两类含吡唑酮或吲哚-2-酮的铬胺衍生物的合成及结构表征:羰基和醛基的反应及化学选择性","authors":"Xuange Zhang, Tianyu Lu, Yan Cai, Zihong Yan, Zhiwei Miao","doi":"10.3866/pku.dxhx201907004","DOIUrl":null,"url":null,"abstract":": Under the catalytic conditions of tetrahydropyrrole, an addition-elimination reaction of chromone aldehyde with methylpyrazolone or 2-indolinone is carried out to obtain two kinds of chromene derivatives containing pyrazolone or indol-2-one. The structures are identified by 1 H NMR, 13 C NMR, HPLC, HRMS and melting point measurements.","PeriodicalId":23447,"journal":{"name":"大学化学","volume":"1 1","pages":""},"PeriodicalIF":0.0000,"publicationDate":"2020-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Synthesis and Structural Characterization of Two Types of Chromene Derivatives Containing Pyrazolone or Indol-2-one: Reaction and Chemoselectivity of Carbonyl and Aldehyde Groups\",\"authors\":\"Xuange Zhang, Tianyu Lu, Yan Cai, Zihong Yan, Zhiwei Miao\",\"doi\":\"10.3866/pku.dxhx201907004\",\"DOIUrl\":null,\"url\":null,\"abstract\":\": Under the catalytic conditions of tetrahydropyrrole, an addition-elimination reaction of chromone aldehyde with methylpyrazolone or 2-indolinone is carried out to obtain two kinds of chromene derivatives containing pyrazolone or indol-2-one. The structures are identified by 1 H NMR, 13 C NMR, HPLC, HRMS and melting point measurements.\",\"PeriodicalId\":23447,\"journal\":{\"name\":\"大学化学\",\"volume\":\"1 1\",\"pages\":\"\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2020-01-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"大学化学\",\"FirstCategoryId\":\"95\",\"ListUrlMain\":\"https://doi.org/10.3866/pku.dxhx201907004\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"大学化学","FirstCategoryId":"95","ListUrlMain":"https://doi.org/10.3866/pku.dxhx201907004","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Synthesis and Structural Characterization of Two Types of Chromene Derivatives Containing Pyrazolone or Indol-2-one: Reaction and Chemoselectivity of Carbonyl and Aldehyde Groups
: Under the catalytic conditions of tetrahydropyrrole, an addition-elimination reaction of chromone aldehyde with methylpyrazolone or 2-indolinone is carried out to obtain two kinds of chromene derivatives containing pyrazolone or indol-2-one. The structures are identified by 1 H NMR, 13 C NMR, HPLC, HRMS and melting point measurements.