两类含吡唑酮或吲哚-2-酮的铬胺衍生物的合成及结构表征:羰基和醛基的反应及化学选择性

Xuange Zhang, Tianyu Lu, Yan Cai, Zihong Yan, Zhiwei Miao
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引用次数: 0

摘要

:在四氢吡咯的催化条件下,铬醛与甲基吡唑啉酮或2-吲哚啉酮进行加消反应,得到两种含吡唑啉酮或吲哚-2-酮的铬衍生物。通过1h NMR, 13c NMR, HPLC, HRMS和熔点测量对其结构进行了鉴定。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Synthesis and Structural Characterization of Two Types of Chromene Derivatives Containing Pyrazolone or Indol-2-one: Reaction and Chemoselectivity of Carbonyl and Aldehyde Groups
: Under the catalytic conditions of tetrahydropyrrole, an addition-elimination reaction of chromone aldehyde with methylpyrazolone or 2-indolinone is carried out to obtain two kinds of chromene derivatives containing pyrazolone or indol-2-one. The structures are identified by 1 H NMR, 13 C NMR, HPLC, HRMS and melting point measurements.
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