Kai Li, 郑州 sup 郑州大学化学与分子工程学院, Huijie Lu, Yuanyuan Li, Shuangquan Zang, B. Tang, 郑州 sup 河南工业大学化学化工与环境学院, 中国 香港 sup 香港科技大学化学系
{"title":"Reimer-Tiemann反应合成聚集诱导发光水杨醛嗪的综合实验","authors":"Kai Li, 郑州 sup 郑州大学化学与分子工程学院, Huijie Lu, Yuanyuan Li, Shuangquan Zang, B. Tang, 郑州 sup 河南工业大学化学化工与环境学院, 中国 香港 sup 香港科技大学化学系","doi":"10.3866/pku.dxhx201904010","DOIUrl":null,"url":null,"abstract":": Aggregation-induced emission (AIE) molecules exhibit intense emission in aggregated state but weak or even no fluorescence in dispersed state. The first AIE molecule was reported in 2001. Since then, various of AIE molecules were developed successively, which were widely applied in fields of photoelectric materials, fluorescence chemosensors and bioimaging, etc . Salicylaldehyde azine is a classic AIE molecule with the merits of simple synthesis and intense luminescence. In this comprehensive experiment, the precursor salicylaldehyde is first synthesized using Reimer-Tiemann reaction. Then it reacts with azine to obtain the AIE molecule of salicylaldehyde azine. Through the experiment, students will practice the synthetic method of Reimer-Tiemann reaction and grasp the origination of AIE characteristics of salicylaldehyde azine. Also, students will learn about the applications of AIE molecules through class and network learning.","PeriodicalId":23447,"journal":{"name":"大学化学","volume":"1 1","pages":""},"PeriodicalIF":0.0000,"publicationDate":"2020-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"A Comprehensive Experiment on Synthesis of Aggregation-Induced Emitting Salicylaldehyde Azine Using Reimer-Tiemann Reaction\",\"authors\":\"Kai Li, 郑州 sup 郑州大学化学与分子工程学院, Huijie Lu, Yuanyuan Li, Shuangquan Zang, B. Tang, 郑州 sup 河南工业大学化学化工与环境学院, 中国 香港 sup 香港科技大学化学系\",\"doi\":\"10.3866/pku.dxhx201904010\",\"DOIUrl\":null,\"url\":null,\"abstract\":\": Aggregation-induced emission (AIE) molecules exhibit intense emission in aggregated state but weak or even no fluorescence in dispersed state. The first AIE molecule was reported in 2001. Since then, various of AIE molecules were developed successively, which were widely applied in fields of photoelectric materials, fluorescence chemosensors and bioimaging, etc . Salicylaldehyde azine is a classic AIE molecule with the merits of simple synthesis and intense luminescence. In this comprehensive experiment, the precursor salicylaldehyde is first synthesized using Reimer-Tiemann reaction. Then it reacts with azine to obtain the AIE molecule of salicylaldehyde azine. Through the experiment, students will practice the synthetic method of Reimer-Tiemann reaction and grasp the origination of AIE characteristics of salicylaldehyde azine. Also, students will learn about the applications of AIE molecules through class and network learning.\",\"PeriodicalId\":23447,\"journal\":{\"name\":\"大学化学\",\"volume\":\"1 1\",\"pages\":\"\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2020-01-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"大学化学\",\"FirstCategoryId\":\"95\",\"ListUrlMain\":\"https://doi.org/10.3866/pku.dxhx201904010\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"大学化学","FirstCategoryId":"95","ListUrlMain":"https://doi.org/10.3866/pku.dxhx201904010","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
A Comprehensive Experiment on Synthesis of Aggregation-Induced Emitting Salicylaldehyde Azine Using Reimer-Tiemann Reaction
: Aggregation-induced emission (AIE) molecules exhibit intense emission in aggregated state but weak or even no fluorescence in dispersed state. The first AIE molecule was reported in 2001. Since then, various of AIE molecules were developed successively, which were widely applied in fields of photoelectric materials, fluorescence chemosensors and bioimaging, etc . Salicylaldehyde azine is a classic AIE molecule with the merits of simple synthesis and intense luminescence. In this comprehensive experiment, the precursor salicylaldehyde is first synthesized using Reimer-Tiemann reaction. Then it reacts with azine to obtain the AIE molecule of salicylaldehyde azine. Through the experiment, students will practice the synthetic method of Reimer-Tiemann reaction and grasp the origination of AIE characteristics of salicylaldehyde azine. Also, students will learn about the applications of AIE molecules through class and network learning.
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