木壳(Batissa violecea L. von Lamark 1818)非均相催化剂在辣木籽油生产生物柴油中的应用

IF 0.5 Q4 EDUCATION & EDUCATIONAL RESEARCH
Ruslan, J. Hardi, M. Mirzan, Muliana, M. Ganti
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引用次数: 0

摘要

Meti壳含有碳酸钙,可煅烧成CaO作为生物柴油合成的多相催化剂。本研究评估了在不同的酯交换时间(1、2、3、3和4小时)下,来自Meti壳的CaO催化剂在1,2,3和4小时浓度下合成辣木籽油生物柴油的能力。在2θ角32.47°、37.74°、54.22°、64.65°和67.67°的衍射处,证实了CaO在Meti壳层中的存在。当CaO浓度为3%,酯交换反应时间为3小时时,得到的Rf值与标准生物柴油的Rf范围一致,分别为0.69和0.66。合成的生物柴油油酸甲酯含量最高,达到59.16%,符合印尼国家标准(SNI 04-7182-2006),其中水分含量为0.004%,酸值为0.06 mgKOH/g,皂化值为273.6 mgKOH/g,碘值为78.678 g碘/100 g,浊点为10℃,倾点为21℃,但十六烷值仍低于最低值51。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
APPLICATION OF HETEROGENEOUS CATALYST OF Meti SHELLS (Batissa violecea L. von Lamark 1818) IN THE PRODUCTION OF BIODIESEL BASED ON MORINGA SEED OIL
Meti shell contains calcium carbonate which can be calcined into CaO and used as a heterogeneous catalyst in biodiesel synthesis. This study evaluated the ability of CaO catalyst from Meti shell with concentrations of 1, 2, 3, 4, and 5% for the synthesis of biodiesel from Moringa seed oil at various transesterification times (1, 2, 3, and 4 hours). The presence of CaO in the Meti shell was indicated by diffraction at 2θ angles of 32.47o , 37.74o , 54.22o , 64.65o , and 67.67oC. Utilizing CaO 3% and a transesterification reaction time of 3 hours resulted in an Rf value corresponding to the standard biodiesel Rf ranges, i.e. 0.69 and 0.66, respectively. The synthesized biodiesel has the highest methyl oleate content of 59.16% with characteristics that have met Indonesian National Standard (SNI 04-7182-2006), including water content of 0.004%, an acid number of 0.06 mg KOH/g, saponification number 273.6 mgKOH/g, iodine number 78.678 g iodine/100 g, the cloud point is 10oC, the pour point is 21oC, however, the cetane number is still below the minimum number of 51.
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来源期刊
Rasayan Journal of Chemistry
Rasayan Journal of Chemistry Energy-Energy (all)
CiteScore
1.90
自引率
0.00%
发文量
196
期刊介绍: RASĀYAN Journal of Chemistry [RJC] signifies a confluence of diverse streams of chemistry to stir up the cerebral powers of its contributors and readers. By introducing the journal by this name, we humbly intent to provide an open platform to all researchers, academicians and readers to showcase their ideas and research findings among the people of their own fraternity and to share their vast repository of knowledge and information. The journal seeks to embody the spirit of enquiry and innovation to augment the richness of existing chemistry literature and theories. We also aim towards making this journal an unparalleled reservoir of information and in process aspire to inculcate and expand the research aptitude.
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