Selective catalytic reduction of NO with ammoniaat low temperature over Cu-promotedand N-modified activated carbon

Catalytic properties of activated carbons oxidized, treated with N-compounds, and promoted with copper were studied in selective catalytic reduction NOX by ammonia (NH3-SCR). The modification of the catalysts consisted of a series of steps (pre-oxidation of activated carbon, impregnation with urea, impregnation with copper). The physicochemical properties of the obtained samples were determined using X-ray diffraction, FT-IR spectroscopy, and low-temperature N2 sorption. The modification with copper improved the catalytic activity and stability of the catalysts. All the functionalized carbon doped with copper reached more than 90% of NO conversion and CO2 did not exceed 240 ppm at 220 ◦C. The sample doped with 5 wt.% Cu had the maximum NO conversion of 98% at 300 ◦C. The maximum N2O concentration detected for the same sample was only 55 ppm, which confirmed its selectivity.