通过碗形三角形螺旋超分子聚集组装纳米级手性球

IF 16.1 1区化学 Q1 CHEMISTRY, MULTIDISCIPLINARY

Angewandte Chemie International Edition Pub Date : 2002-11-12 DOI:10.1002/1521-3773(20021115)41:22<4244::AID-ANIE4244>3.0.CO;2-5

Laura J. Childs, Nathaniel W. Alcock Dr., Michael J. Hannon Dr.

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引用次数: 81

摘要

碗到球:三角碗形铜(I)圆形螺旋基于吡啶胺配体是通过混合现成的试剂组装。三角形的碗状地形控制了其中四个单元的超分子聚集，形成手性四聚体球形结构(见图)，通过面缘(CH⋅⋅π) π相互作用和CH⋅⋅⋅F相互作用结合在一起。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Assembly of a Nanoscale Chiral Ball through Supramolecular Aggregation of Bowl-Shaped Triangular Helicates†

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Assembly of a Nanoscale Chiral Ball through Supramolecular Aggregation of Bowl-Shaped Triangular Helicates†

Bowls to balls: Triangular bowl-shaped copper(I) circular helicates based on pyridylimine ligands are assembled by mixing readily available reagents. The bowl-shaped topography of the triangles controls the supramolecular aggregation of four of these units into a chiral tetrameric ball-shaped structure (see picture) held together by face–edge (CH⋅⋅⋅π) π interactions and CH⋅⋅⋅F interactions.

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来源期刊

Angewandte Chemie International Edition 化学-化学综合

CiteScore

26.60

自引率

6.60%

发文量

3549

审稿时长

1.5 months

期刊介绍： Angewandte Chemie, a journal of the German Chemical Society (GDCh), maintains a leading position among scholarly journals in general chemistry with an impressive Impact Factor of 16.6 (2022 Journal Citation Reports, Clarivate, 2023). Published weekly in a reader-friendly format, it features new articles almost every day. Established in 1887, Angewandte Chemie is a prominent chemistry journal, offering a dynamic blend of Review-type articles, Highlights, Communications, and Research Articles on a weekly basis, making it unique in the field.